We investigated the use of multispectral thermal imagery to retrieve land surface emissivity and temperature. Conversely to concurrent methods, the temperature emissivity separation (TES) method simply requires single overpass without any ancillary information. This is possible since TES makes use of an empirical relationship that estimates the minimum emissivity ε-min from the emissivity spectral contrast captured over several channels, so-called maximum-minimum difference (MMD). In previous studies, the ε-min - MMD empirical relationship of TES was calibrated and validated for various sensor spectral configurations, where the proposed calibrations involved single or linearly mixed spectra of emissivity at the leaf or soil level. However, ...