The tricyclic terpenoid (±)-hirsutene (1) has been synthesized starting from 2-hydroxy-4,4-dimethyltetrahydropyrane (8). In the key step, acyclic enynyl carbonate 7 afforded bicyclooctenone 2 via a 85% diastereoselective palladium catalyzed metallo-ene/carbonylation reaction cascade. The third ring was closed by a radical/alkene addition 19 → 20
The first chapter describes the synthesis of curvulone B featuring a strategy of cross metathesis an...
An antibiotic lissoclinolide has been synthesized in 9 steps and 32% overall yield via (i) hydrogen ...
Two new and general strategies for the preparation of bridged and fused polycarbocyclic terpenoids h...
This account describes a strategy for directly forming three of the six rings found in the polyketid...
This account describes a strategy for directly forming three of the six rings found in the polyketid...
Dual total syntheses of (±)-hirsutene and (±)-capnellene, two typical linear triquinane sesquiterpen...
Dual total syntheses of (±)-hirsutene and (±)-capnellene, two typical linear triquinane sesquiterpen...
A total synthesis of hirsutene, a tricyclic sesquiterpene, from saligenin, is described.© Elsevie
The first total synthesis of the hirsutene-type sesquiterpenoid natural product (+)-connatusin B (2)...
Formal syntheses of hirsutic acid C and complicatic acid via cycloaddition of cyclohexa-2,4-dienone ...
The intramolecular cyclopentene annulation methodology which combines the cyclopropanation of dienic...
In this thesis work, an extensive study was carried out on the Pd-catalyzed cross-coupling between o...
Two new and general strategies for the preparation of bridged and fused polycarbocyclic terpenoids h...
Aryl and alkenylpalladium compounds generated by oxidative addition of a palladium(0) catalyst to th...
Two new and general strategies for the preparation of bridged and fused polycarbocyclic terpenoids h...
The first chapter describes the synthesis of curvulone B featuring a strategy of cross metathesis an...
An antibiotic lissoclinolide has been synthesized in 9 steps and 32% overall yield via (i) hydrogen ...
Two new and general strategies for the preparation of bridged and fused polycarbocyclic terpenoids h...
This account describes a strategy for directly forming three of the six rings found in the polyketid...
This account describes a strategy for directly forming three of the six rings found in the polyketid...
Dual total syntheses of (±)-hirsutene and (±)-capnellene, two typical linear triquinane sesquiterpen...
Dual total syntheses of (±)-hirsutene and (±)-capnellene, two typical linear triquinane sesquiterpen...
A total synthesis of hirsutene, a tricyclic sesquiterpene, from saligenin, is described.© Elsevie
The first total synthesis of the hirsutene-type sesquiterpenoid natural product (+)-connatusin B (2)...
Formal syntheses of hirsutic acid C and complicatic acid via cycloaddition of cyclohexa-2,4-dienone ...
The intramolecular cyclopentene annulation methodology which combines the cyclopropanation of dienic...
In this thesis work, an extensive study was carried out on the Pd-catalyzed cross-coupling between o...
Two new and general strategies for the preparation of bridged and fused polycarbocyclic terpenoids h...
Aryl and alkenylpalladium compounds generated by oxidative addition of a palladium(0) catalyst to th...
Two new and general strategies for the preparation of bridged and fused polycarbocyclic terpenoids h...
The first chapter describes the synthesis of curvulone B featuring a strategy of cross metathesis an...
An antibiotic lissoclinolide has been synthesized in 9 steps and 32% overall yield via (i) hydrogen ...
Two new and general strategies for the preparation of bridged and fused polycarbocyclic terpenoids h...
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