Effective medium theories for nanocomposite characterization

A methodology to retrieve the dielectric function of a nanocomposite from infrared spectroscopy is presented. The use of effective medium theories allows treating the optical response of a multi-phase composite as that of a single phase with an effective response that is a complex function of the components and their spatial arrangement. This methodology has been tested in a case study involving cerium oxide nanoparticles, whose vibrational properties are known to change significantly upon particle size reduction. Accurate values of its dielectric function in the infrared have been retrieved and used to analyse this phenomenon. The main goal of this study is to develop a systematic methodology for the study of the vibrational properties of nanomaterials. It is also intended that the development of effective medium models will be useful for designing new composite nanomaterials with improved optical properties (e.g., solar absorbers)