The chapter one introduces the reported examples of rare earth metal (RE) complexes with different oxidation states. It also reviews the synthesis and reactivity study of N-heterocyclic carbene (NHC) supported transition metal and RE metal complexes. Chapter two focusses on the synthesis and characterisation of a series of tetraaryloxide Ce and Pr complexes. With the reaction of bulky tetraphenol proligand H4LR(R = P, PT, M) with four equivalents of KN"(N" = N(SiMe3)2), a dimerised complex of [K4LP]2(thf)11 was synthesised and characterised. The salt metathesis reactions of this complex with RECl3(thf)2 afford bimetallic aryloxide complexes of K2L2RE2(thf)11 (RE = Ce, Pr), which display divergent structures under different conditions. Reac...
This thesis focuses on the synthesis of early transition metal complexes. A unique series of chromiu...
This thesis focuses on the synthesis of early transition metal complexes. A unique series of chromiu...
The focus of this Thesis is on the synthesis and characterisation of aryloxides of the lanthanoid an...
The first chapter is an introduction to the f-elements, with a focus on the synthesis and chemistry ...
The combination of Lewis acidic f-block metals and a labile nucleophilic carbene can be an excellen...
This dissertation describes the synthesis, characterization, and reactivity of organometallic comple...
This dissertation describes the synthesis, characterization, and reactivity of organometallic comple...
This dissertation describes an expansion of reductive rare-earth metal chemistry focused on the synt...
This dissertation focuses on efforts to expand upon the discovery that the +2 oxidation state is ava...
This dissertation describes an expansion of reductive rare-earth metal chemistry focused on the synt...
The first chapter is an introduction to the f-elements, with a focus on the synthesis and chemistry...
This dissertation describes the synthesis, physical characterization, and reactivity of new classes ...
This dissertation describes the synthesis, physical characterization, and reactivity of new classes ...
This thesis focuses on the synthesis of early transition metal complexes. A unique series of chromiu...
This thesis focuses on the synthesis of early transition metal complexes. A unique series of chromiu...
This thesis focuses on the synthesis of early transition metal complexes. A unique series of chromiu...
This thesis focuses on the synthesis of early transition metal complexes. A unique series of chromiu...
The focus of this Thesis is on the synthesis and characterisation of aryloxides of the lanthanoid an...
The first chapter is an introduction to the f-elements, with a focus on the synthesis and chemistry ...
The combination of Lewis acidic f-block metals and a labile nucleophilic carbene can be an excellen...
This dissertation describes the synthesis, characterization, and reactivity of organometallic comple...
This dissertation describes the synthesis, characterization, and reactivity of organometallic comple...
This dissertation describes an expansion of reductive rare-earth metal chemistry focused on the synt...
This dissertation focuses on efforts to expand upon the discovery that the +2 oxidation state is ava...
This dissertation describes an expansion of reductive rare-earth metal chemistry focused on the synt...
The first chapter is an introduction to the f-elements, with a focus on the synthesis and chemistry...
This dissertation describes the synthesis, physical characterization, and reactivity of new classes ...
This dissertation describes the synthesis, physical characterization, and reactivity of new classes ...
This thesis focuses on the synthesis of early transition metal complexes. A unique series of chromiu...
This thesis focuses on the synthesis of early transition metal complexes. A unique series of chromiu...
This thesis focuses on the synthesis of early transition metal complexes. A unique series of chromiu...
This thesis focuses on the synthesis of early transition metal complexes. A unique series of chromiu...
The focus of this Thesis is on the synthesis and characterisation of aryloxides of the lanthanoid an...