Add to ORKGA family of permethylindenyl titanium constrained geometry complexes, Me2SB(R′N,3-RI*)TiX2 ((3-R-η5-C9Me5)Me2Si(R′TiX2)), supported on solid polymethylaluminoxane (sMAO) are investigated as slurry-phase catalysts for ethylene/H2 homopolymerisation and ethylene/1-hexene copolymerisation by high-throughput catalyst screening. Me2SB(tBuN,I*)TiCl2 supported on sMAO [sMAO-Me2SB(tBuN,I*)TiCl2] is responsive to small quantities of H2 (<1.6%), maintaining high polymerisation activities (up to 4900 kgPE molTi−1 h−1 bar−1) and yielding polyethylenes with significantly decreased molecular weight (Mw) (from 2700 to 41 kDa with 1.6% H2). In slurry-phase ethylene/1-hexene copolymerisation studies, a decrease in polymerisation activity and polymer molecul...
Supported olefin polymerization catalysts can prevent reactor-fouling problems and produce uniform p...
A series of titanium (IV) complexes 3a-f stabilized by 1,2-diolate ligands 2 a-e have been synthesiz...
The selective and high-yielding synthesis of fully amorphous ultra-high molecular weight atactic pol...
Novel permethylindenyl-phenoxide (PHENI*) ansa-metallocene titanium complexes have been synthes...
New catatytic systems based on N,N-dialkylcarbamato Ti(IV) precursors for copolymerization of ethyle...
A new type of post-metallocene polymerization catalyst based on titanium complexes with N,N-dialkylc...
The synthesis of polymers of 10 million or more molecular weight is a difficult task even in a chemi...
A series of ten well-defined group 4 ansa-bridged permethylindenyl complexes have been prepared, ful...
This thesis discusses the development of permethylindenyl constrained geometry complexes (CGCs) as h...
We report the synthesis and characterisation of eight constrained geometry complexes, with variation...
Octahedral group IV bis(phenolate) catalysts are highly active catalysts for the isospecific polyme...
Complex cations with a vacant coordination site are considered as the most plausible catalytically a...
New alkoxo-titanium(IV) complexes with diolate ligand containing additional donor oxygen atom have b...
\u3cp\u3eA silica-supported tandem catalyst system, capable of producing ethylene/1-hexene copolymer...
The primary aims of the thesis were to: (i) discover catalyst systems that maintained high α-olefin ...
Supported olefin polymerization catalysts can prevent reactor-fouling problems and produce uniform p...
A series of titanium (IV) complexes 3a-f stabilized by 1,2-diolate ligands 2 a-e have been synthesiz...
The selective and high-yielding synthesis of fully amorphous ultra-high molecular weight atactic pol...
Novel permethylindenyl-phenoxide (PHENI*) ansa-metallocene titanium complexes have been synthes...
New catatytic systems based on N,N-dialkylcarbamato Ti(IV) precursors for copolymerization of ethyle...
A new type of post-metallocene polymerization catalyst based on titanium complexes with N,N-dialkylc...
The synthesis of polymers of 10 million or more molecular weight is a difficult task even in a chemi...
A series of ten well-defined group 4 ansa-bridged permethylindenyl complexes have been prepared, ful...
This thesis discusses the development of permethylindenyl constrained geometry complexes (CGCs) as h...
We report the synthesis and characterisation of eight constrained geometry complexes, with variation...
Octahedral group IV bis(phenolate) catalysts are highly active catalysts for the isospecific polyme...
Complex cations with a vacant coordination site are considered as the most plausible catalytically a...
New alkoxo-titanium(IV) complexes with diolate ligand containing additional donor oxygen atom have b...
\u3cp\u3eA silica-supported tandem catalyst system, capable of producing ethylene/1-hexene copolymer...
The primary aims of the thesis were to: (i) discover catalyst systems that maintained high α-olefin ...
Supported olefin polymerization catalysts can prevent reactor-fouling problems and produce uniform p...
A series of titanium (IV) complexes 3a-f stabilized by 1,2-diolate ligands 2 a-e have been synthesiz...
The selective and high-yielding synthesis of fully amorphous ultra-high molecular weight atactic pol...