Speeding up Dynamics by Tuning the Noncommensurate Size of Rodlike Particles in a Smectic Phase

Using simulations, we study the diffusion of rodlike guest particles in a smectic environment of rodlike host particles. We find that the dynamics of guest rods across smectic layers changes from a fast nematiclike diffusion to a slow hopping-type dynamics via an intermediate switching regime by varying the length of the guest rods with respect to the smectic layer spacing. We determine the optimal rod length that yields the fastest and the slowest diffusion in a lamellar environment. We show that this behavior can be rationalized by a complex 1D effective periodic potential exhibiting two energy barriers, resulting in a varying preferred mean position of the guest particle in the smectic layer. The interplay of these two barriers controls the dynamics of the guest particles yielding a slow, an intermediate, and a fast diffusion regime depending on the particle length