Measurement of the linear viscoelastic behavior of antimisting kerosene

Measurements of dynamic viscoelastic properties in very small oscillating shear deformations was made on solutions of a jet fuel, Jet A, containing an antimisting polymeric additive, FM-9. A few measurements were also made on solutions of FM-9 in a mixed solvent of mineral oil, Tetralin, and 0-terphenyl. Two samples of FM-9 had approximate number-average molecular weights of 12,000,000 and 8,100,000 as deduced from analysis of the measurements. The ranges of variables were 2.42 to 4.03 g/1 in concentration (0.3 to 0.5% by weight), 1 to 35 in temperature, 1.3 to 9.4 cp in solvent viscosity, and 103 to 6100 Hz in frequency. Measurements in the Jet A solvent were made both with and without a modifying carrier. The results were compared with the Zimm theory and the viscoelastic behavior was found to resemble rather closely that of ordinary non-polar polymers in theta solvents. The relation of the results to the antithixotropic behavior of such solutions a high shear rates is discussed in terms of intramolecular and intermolecular interactions