The role of ruthenium as a heterogeneous catalyst for epoxidation reaction has not been investigated extensively. Therefore, the purpose of this chapter is to provide overview of the epoxidation of alkene using ruthenium catalysts. The chapter is divided into two main sections. The first section is about epoxidation of alkene using supported ruthenium catalysts, while the second using ruthenium complexes (homogenous catalysts)
A polybenzimidazole supported Mo(VI) (PBI.Mo) catalyst has been prepared and characterised. The cata...
[[abstract]]Treatment of (o-ethynyl)phenyl epoxides with TpRuPPh(3)(CH3CN)(2)PF6 (10 mol%) in hot to...
Aldehydes in excellent yields were obtained from the ruthenium-porphyrin- catalyzed oxidation of var...
Epoxidation of alkenes by molecular oxygen is effected in high yields by catalysis of RuCl2(biox)2 u...
The complex [Ru(III)(Me3tacn)(OH2)2(CF3CO2)](CF3CO2)2 (Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclono...
This account describes our efforts to heterogenize epoxidation catalysts. Anchored and sol-gel entra...
A new methodology has been developed for the catalytic epoxidation of cyclic vinylsilanes using a ru...
Coordinatively unsaturated complexes of ruthenium(I1) of the type [RUCI(LL)~]+w,h ere LL is 1,3-bis(...
Reaction of [RuCl2(NCMe)2(cod)] with bis(dihydrooxazoles) gave [RuCl2(cod)(S,S)-R12C-(C=NCHR 2CR12O)...
The X-ray crystal structure of a dimethyl sulfoxide (DMSO) coordinating complex [Ru<sup>II</sup>(κ<s...
Nestled between the noble and non-noble metals in the periodic table, ruthenium, one of the transiti...
Abstract: Ruthenium, rhodium, iridium, and rhenium hydride complexes are highly useful redox Lewis a...
The present work shows the catalytic activity of a series of carbonyl ruthenium complexes in the epo...
Carbonyl ruthenium(II) 5,10,15-tris(4-R-phenyl)-20-(4- hydroxyphenyl)porphyrins (R = Cl, Me) covalen...
A new ruthenium aquo catalyst with the formula trans-[Ru(II)(CN-Me)(trpy) OH2](PF6)2 [where trpy=2,2...
A polybenzimidazole supported Mo(VI) (PBI.Mo) catalyst has been prepared and characterised. The cata...
[[abstract]]Treatment of (o-ethynyl)phenyl epoxides with TpRuPPh(3)(CH3CN)(2)PF6 (10 mol%) in hot to...
Aldehydes in excellent yields were obtained from the ruthenium-porphyrin- catalyzed oxidation of var...
Epoxidation of alkenes by molecular oxygen is effected in high yields by catalysis of RuCl2(biox)2 u...
The complex [Ru(III)(Me3tacn)(OH2)2(CF3CO2)](CF3CO2)2 (Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclono...
This account describes our efforts to heterogenize epoxidation catalysts. Anchored and sol-gel entra...
A new methodology has been developed for the catalytic epoxidation of cyclic vinylsilanes using a ru...
Coordinatively unsaturated complexes of ruthenium(I1) of the type [RUCI(LL)~]+w,h ere LL is 1,3-bis(...
Reaction of [RuCl2(NCMe)2(cod)] with bis(dihydrooxazoles) gave [RuCl2(cod)(S,S)-R12C-(C=NCHR 2CR12O)...
The X-ray crystal structure of a dimethyl sulfoxide (DMSO) coordinating complex [Ru<sup>II</sup>(κ<s...
Nestled between the noble and non-noble metals in the periodic table, ruthenium, one of the transiti...
Abstract: Ruthenium, rhodium, iridium, and rhenium hydride complexes are highly useful redox Lewis a...
The present work shows the catalytic activity of a series of carbonyl ruthenium complexes in the epo...
Carbonyl ruthenium(II) 5,10,15-tris(4-R-phenyl)-20-(4- hydroxyphenyl)porphyrins (R = Cl, Me) covalen...
A new ruthenium aquo catalyst with the formula trans-[Ru(II)(CN-Me)(trpy) OH2](PF6)2 [where trpy=2,2...
A polybenzimidazole supported Mo(VI) (PBI.Mo) catalyst has been prepared and characterised. The cata...
[[abstract]]Treatment of (o-ethynyl)phenyl epoxides with TpRuPPh(3)(CH3CN)(2)PF6 (10 mol%) in hot to...
Aldehydes in excellent yields were obtained from the ruthenium-porphyrin- catalyzed oxidation of var...