β″-(BEDT-TTF)[(HO)Cr(CO )]CHCl: Effect of included solvent on the structure and properties of a conducting molecular charge-transfer salt
- Rashid, S
- Turner, SS
- Le Pevelen, D
- Day, P
- Light, ME
- Hursthouse, MB
- Firth, S
- Clark, RJH
DOIAbstract
The new charge-transfer salt β″-(BEDT-TTF)[(HO)Cr(CO )]S, where BEDT-TTF = bis-(ethylenedithio)tetrathiafulvalene and S = CHCl has a broad metal-insulator transition at approximately 150 K. This differs from similar salts in the BEDT-TTF tris(oxalato) metalate series, notably the superconducting materials with S = PhCN and the salt with S = CHN, which has a sharp metal-insulator transition
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