New Chiral BINOL‐Based Phosphates for Enantioselective [Au(I)]‐Catalyzed Dearomatization of β‐Naphthols with Allenamides

open4noNew chiral BINOL-based phosphate counterions have been synthesized, fully characterized, and employed in the enantioselective gold-catalyzed dearomatization of -naphthols with allenamides. A range of densely functionalized C1-allylated naphthalenones were realized under mild conditions and high levels of chemo-, regio- and stereoselectivity (ee up to 95 %).partially_openembargoed_20210314Riccardo Pedrazzani, Juzeng An, Magda Monari, Marco BandiniRiccardo Pedrazzani, Juzeng An, Magda Monari, Marco Bandin