This paper presents the first large-scale investigation of the users and uses of WorldCat.org, the world’s largest bibliographic database and global union catalogue. Using a mixed-methods approach involving focus group interviews with 120 participants, an online survey with 2,918 responses, and an analysis of transaction logs of approximately 15 million sessions from WorldCat.org, the study provides a new understanding of the context for global union catalogue use. We find that WorldCat.org is accessed by diverse population, with the three primary user groups being librarians, students and academics. Use of the system is found to fall within three broad types of work-task (professional, academic, and leisure), and we also present an e...