Titanium and zirconium complexes containing a novel dianionic trifunctional amido ligand
- Friedrich, S.
- Schubart, M.
- Gade, L. H.
- Scowen, I. J.
- Edwards, A. J.
- McPartlin, M.
Publication date
December 1997
DOI Publisher
Wiley ISSN
0009-2940 Citation count (estimate)
31Abstract
The novel tridentate diamidoamine ligands RC(2-C5H4N)(CH2NSiMe3) 22- (R = H, CH3) have been synthesized and coordinated to TiIV and ZrIV giving the pentacoordinate complexes MX2(RC(2-C5H4N)(CH2NSiMe 3)2 (M = Ti, Zr; X = Cl, Br). The crystal structure analysis of TiBr2(HC(2-C5H4N)(CH2NSiMe 3
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