Add to ORKGSeveral ketones and aldehydes were hydrogenated with Frustrated Lewis pair (FLP) conditions using microwave irradiation. Several of these products were characterized by spectroscopic techniques. Cyclopentyl methyl ether (CPME) was found to be the most efficient solvent under microwave conditions. Stereoselectivity of hydride addition was varied with cyclohexanone derivatives and depended on the proximity of large groups to the electrophilic center. The reaction rates of benzaldehyde and acetophenone derivatives were calculated to compare effects of electron withdrawing groups. The use of the microwave successfully reduced reaction times from several hours to just a few minutes in the most extreme cases
Microwave heating has seen increasing use in synthetic organic chemistry ever since the first publis...
In this thesis paper, three new procedures for benzoylation reactions were developed using microwave...
In the Conventional laboratory or industry heating technique involve Bunsen burner, heating mental/h...
The area of chemical research and synthesis increasingly recognises the need for improved technologi...
Microwave irradiation has gained in popularity in recent years since it has been found to accelerate...
The use of solvents in organic synthesis is today one of the main causes of pollution and risk for h...
This research was prompted by the growing body of information accumulating in the literature which r...
Kinetic studies were conducted on three unrelated reaction types using traditional and modified reac...
ABSTRACT: Hydrogenation of alkyl and aryl ketones using H2 is catalytically achieved in 18 examples ...
[EN] It is nowadays admitted that microwaves are frequently used in organic chemistry labs [1] (even...
This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project ...
The use of dielectric spectroscopy to develop an underpinning understanding of the molecular transfo...
Microwave irradiation is a well-accepted heating technique for lab-scale organic synthesis but its a...
The method of microwave-assisted synthesis of benzylidenemalononitrile and its derivatives by using ...
The work presented in this thesis concerns the use of Lewis acidic compounds based upon the main-gro...
Microwave heating has seen increasing use in synthetic organic chemistry ever since the first publis...
In this thesis paper, three new procedures for benzoylation reactions were developed using microwave...
In the Conventional laboratory or industry heating technique involve Bunsen burner, heating mental/h...
The area of chemical research and synthesis increasingly recognises the need for improved technologi...
Microwave irradiation has gained in popularity in recent years since it has been found to accelerate...
The use of solvents in organic synthesis is today one of the main causes of pollution and risk for h...
This research was prompted by the growing body of information accumulating in the literature which r...
Kinetic studies were conducted on three unrelated reaction types using traditional and modified reac...
ABSTRACT: Hydrogenation of alkyl and aryl ketones using H2 is catalytically achieved in 18 examples ...
[EN] It is nowadays admitted that microwaves are frequently used in organic chemistry labs [1] (even...
This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project ...
The use of dielectric spectroscopy to develop an underpinning understanding of the molecular transfo...
Microwave irradiation is a well-accepted heating technique for lab-scale organic synthesis but its a...
The method of microwave-assisted synthesis of benzylidenemalononitrile and its derivatives by using ...
The work presented in this thesis concerns the use of Lewis acidic compounds based upon the main-gro...
Microwave heating has seen increasing use in synthetic organic chemistry ever since the first publis...
In this thesis paper, three new procedures for benzoylation reactions were developed using microwave...
In the Conventional laboratory or industry heating technique involve Bunsen burner, heating mental/h...