A new cobaloxime-type model for coenzyme B<sub>12</sub> has been synthesized. For this model strong steric repulsion between its dioxymethylene bridge and (one of) the axial ligands on cobalt presages enhanced rates of axial ligand exchange
In addition to key aspects of B12 chemistry, both historical and recent advances in B12 biology and ...
2-Cyclopropyl succinic acid has been prepared from cyclopropyl carbinol. This compound was designed ...
Vitamin B12 catalyses a variety of important reactions in metabolic pathways. Impairment of vitamin ...
The synthesis of a new Costa-type ligand (H2mdo), in which the propylene bridge has been replaced by...
2021-2025The equilibrium, kinetics and thermodynamic parameters of axial ligand substitution of cob...
Department of Chemistry, Osmania University, Hyderabad-500 007, India E-mail : ssnsirasani@yahoo.co...
A novel reaction between norbornene and the cobalt(II) complex of the tetraazamacrocyclic ligand 5,1...
Department of Chemistry, Nizam College, Hyderabad-500 001, India E-mail : ssnsirasani@gmail.com De...
2081-2086Equilibria and kinetics of the reaction of trifluoroethyl(aquo)cobaloximes with imidazole ...
A model for cobalamin was synthesized using a new monoanionic tetradentate nitrogen donor ligand; 2-...
International audienceDensity functional theory (DFT) calculations (BP86/6-31+G(d,p)) and an analysi...
This communication describes the stabilizing effect (ΔΔG° = −4 kJ mol$^{^−1}$) of a remote methyl gr...
The interligand interactions in coordination compounds have been principally interpreted in terms of...
The synthesis of a Co(III) corrole, [10-(2-[[4-(1<i>H</i>-imidazol-1-ylmethyl)benzoyl]amino]phen...
International audienceThe synthesis of a Co(III) corrole, [10-(2-[[4-(1H-imidazol-1-ylmethyl)benzoyl...
In addition to key aspects of B12 chemistry, both historical and recent advances in B12 biology and ...
2-Cyclopropyl succinic acid has been prepared from cyclopropyl carbinol. This compound was designed ...
Vitamin B12 catalyses a variety of important reactions in metabolic pathways. Impairment of vitamin ...
The synthesis of a new Costa-type ligand (H2mdo), in which the propylene bridge has been replaced by...
2021-2025The equilibrium, kinetics and thermodynamic parameters of axial ligand substitution of cob...
Department of Chemistry, Osmania University, Hyderabad-500 007, India E-mail : ssnsirasani@yahoo.co...
A novel reaction between norbornene and the cobalt(II) complex of the tetraazamacrocyclic ligand 5,1...
Department of Chemistry, Nizam College, Hyderabad-500 001, India E-mail : ssnsirasani@gmail.com De...
2081-2086Equilibria and kinetics of the reaction of trifluoroethyl(aquo)cobaloximes with imidazole ...
A model for cobalamin was synthesized using a new monoanionic tetradentate nitrogen donor ligand; 2-...
International audienceDensity functional theory (DFT) calculations (BP86/6-31+G(d,p)) and an analysi...
This communication describes the stabilizing effect (ΔΔG° = −4 kJ mol$^{^−1}$) of a remote methyl gr...
The interligand interactions in coordination compounds have been principally interpreted in terms of...
The synthesis of a Co(III) corrole, [10-(2-[[4-(1<i>H</i>-imidazol-1-ylmethyl)benzoyl]amino]phen...
International audienceThe synthesis of a Co(III) corrole, [10-(2-[[4-(1H-imidazol-1-ylmethyl)benzoyl...
In addition to key aspects of B12 chemistry, both historical and recent advances in B12 biology and ...
2-Cyclopropyl succinic acid has been prepared from cyclopropyl carbinol. This compound was designed ...
Vitamin B12 catalyses a variety of important reactions in metabolic pathways. Impairment of vitamin ...
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