The Engineering and Physical Sciences Research Council and the European Research Council are acknowledged for financial support.This is the accepted manuscript of a paper published in Chemical Reviews (McConnell AJ, Wood CS, Neelakandan PP, Nitschke JR, Chemical Reviews (2015) 115(15):7729-7793. doi:10.1021/cr500632f). The final version is available at http://dx.doi.org/10.1021/cr500632
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