Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II).
- Tuxworth, Luke
- Baiget, Lise
- Phanopoulos, Andreas
- Metters, Owen J.
- Batsanov, Andrei S.
- Fox, Mark A.
- Howard, Judith A. K.
- Dyer, Philip W.
Publication date
September 2012
DOI Publisher
Royal Society of Chemistry (RSC) ISSN
1359-7345 Journal
Chemical Communications Language
English Citation count (estimate)
5Abstract
N-Diphenylphosphino-7-aza-benzobicyclo[2.2.1]hept-2-ene (2) behaves as a chelating phosphine–alkene ligand for Pd0 and PdII, promoting direct alkyl–alkyl and indirect alkyl–halide reductive elimination reactions due to the stabilisation of the resulting bis(phosphine–alkene)Pd0 complex
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