Fifteen C-diazaborolyl-ortho-carboranes, 1-R′-2-R′′-1,2-C2B10H10, where R′ represents the groups 2-(1,3-Et2-1,3,2-N2BC6H4)-, 2-(1,3-Ph2-1,3,2-N2BC6H4)-, 2-(1,3-Ph2-5,6-Me2-1,3,2-N2BC6H2)-, 2-(1,3-iPr2-1,3,2-N2BC6H4)-, and 2-(1,3,2-N2BC6H6)- and where R′′ is H, Me, Ph, tBu or SiMe3, were synthesized. Cyclic voltammetry studies of the compounds showed irreversible oxidation waves which are caused by the oxidation of the heterocycle. Those C-diazaborolyl-ortho-carboranes with Ph, tBu and SiMe3 substituents at the adjacent C-atom of the cage displayed two one-electron reduction waves reflecting the formation of stable radical monoanions with unusual (2n + 3) skeletal electron counts. The geometries of these anions were determined by combination...
Seventeen compounds including the parent ortho-, meta- and para-carboranes and derivatives of ortho-...
Six new C,C′-bis(benzodiazaborolyl)dicarba-closo-dodecaboranes, 1,A-R2-1,A-C2B10H10, where R represe...
Four brand new hybrid ligands combining an N-heterocyclic carbene tethered with two isomeric nido-di...
Fifteen C-diazaborolyl-ortho-carboranes, 1-R′-2-R′′-1,2-C2B10H10, where R′ represents the groups 2-(...
Weber L, Kahlert J, Böhling L, et al. Electrochemical and spectroelectrochemical studies of C-benzod...
One-electron reduction of the well-known carborane 1,2-Ph2-1,2-C2B10H10 (1) gives rise to a stable c...
Six new C,C′-bis(benzodiazaborolyl)dicarba-closo-dodecaboranes, 1,A-R2-1,A-C2B10H10, where R represe...
While carboranes with 2 n+2 and 2 n+4 (n=number of skeletal atoms) skeletal electrons (SE) are widel...
The influence of aryl ring substituents X (F, OMe, NMe2, NH2, OH and O−) on the physical and electro...
Details are reported of the preparation and X-ray structural characterisation of the new compounds (...
One-electron reduction of the well-known carborane 1,2-Ph2-1,2-C2B10H10 (1) gives rise to a stable c...
Six new C,C′-bis(benzodiazaborolyl)dicarba-closo-dodecaboranes, 1,A-R2-1,A-C2B10H10, where R represe...
The icosahedral carboranes 1-C6F5-2-Ph-1,2-closo-C2B10H10 (1), 1-(4'-F3CC6H4)-2-Ph-1,2-closo-C2B10H1...
Six new C,C′-bis(benzodiazaborolyl)dicarba-closo-dodecaboranes, 1,A-R2-1,A-C2B10H10, where R represe...
The icosahedral carboranes 1-C6F5-2-Ph-1,2-closo-C2B10H10 (1), 1-(4'-F3CC6H4)-2-Ph-1,2-closo-C2B10H1...
Seventeen compounds including the parent ortho-, meta- and para-carboranes and derivatives of ortho-...
Six new C,C′-bis(benzodiazaborolyl)dicarba-closo-dodecaboranes, 1,A-R2-1,A-C2B10H10, where R represe...
Four brand new hybrid ligands combining an N-heterocyclic carbene tethered with two isomeric nido-di...
Fifteen C-diazaborolyl-ortho-carboranes, 1-R′-2-R′′-1,2-C2B10H10, where R′ represents the groups 2-(...
Weber L, Kahlert J, Böhling L, et al. Electrochemical and spectroelectrochemical studies of C-benzod...
One-electron reduction of the well-known carborane 1,2-Ph2-1,2-C2B10H10 (1) gives rise to a stable c...
Six new C,C′-bis(benzodiazaborolyl)dicarba-closo-dodecaboranes, 1,A-R2-1,A-C2B10H10, where R represe...
While carboranes with 2 n+2 and 2 n+4 (n=number of skeletal atoms) skeletal electrons (SE) are widel...
The influence of aryl ring substituents X (F, OMe, NMe2, NH2, OH and O−) on the physical and electro...
Details are reported of the preparation and X-ray structural characterisation of the new compounds (...
One-electron reduction of the well-known carborane 1,2-Ph2-1,2-C2B10H10 (1) gives rise to a stable c...
Six new C,C′-bis(benzodiazaborolyl)dicarba-closo-dodecaboranes, 1,A-R2-1,A-C2B10H10, where R represe...
The icosahedral carboranes 1-C6F5-2-Ph-1,2-closo-C2B10H10 (1), 1-(4'-F3CC6H4)-2-Ph-1,2-closo-C2B10H1...
Six new C,C′-bis(benzodiazaborolyl)dicarba-closo-dodecaboranes, 1,A-R2-1,A-C2B10H10, where R represe...
The icosahedral carboranes 1-C6F5-2-Ph-1,2-closo-C2B10H10 (1), 1-(4'-F3CC6H4)-2-Ph-1,2-closo-C2B10H1...
Seventeen compounds including the parent ortho-, meta- and para-carboranes and derivatives of ortho-...
Six new C,C′-bis(benzodiazaborolyl)dicarba-closo-dodecaboranes, 1,A-R2-1,A-C2B10H10, where R represe...
Four brand new hybrid ligands combining an N-heterocyclic carbene tethered with two isomeric nido-di...