An expedient and reliable method for accessing reactive alpha-oxo gold carbenes via gold-catalyzed intermolecular oxidation of terminal alkynes has been developed. Significantly, this method offers a safe and economical alternative to the strategies based on diazo substrates. Its synthetic potential is demonstrated by expedient preparation of dihydrofuran-3-ones containing a broad range of functional groups
In recent years, gold(I) complexes have seen increased use as catalysts for the activation of alkyne...
A facile gold-catalyzed oxidation terminal alkynes to synthesize substituted dihydronaphthalen-2(1<...
Gold-catalyzed intramolecular oxidation of terminal alkynes with an arenesulfinyl group as the tethe...
For the past dozen years, homogeneous gold catalysis has evolved from a little known topic in organi...
F or the past dozen years, homogeneous gold catalysis has evolved from a little known topic in organ...
Donor-substituted acyl gold carbenes are challenging to access selectively by gold-promoted intermol...
In the presence of a gold catalyst an unprecedented oxidative cyclization of diynes takes place. The...
Inductive perturbations of C-C triple bonds are shown to dictate the regiochemistry of gold-catalyze...
Alkynes and allenes are one of the most readily available starting materials having ??-bonds. Electr...
The iodination of terminal alkynes for the synthesis of 1-iodoalkynes using N-iodosuccinimide in the...
Recent years have witnessed a tremendous growth in the number of gold-catalyzed highly selective che...
In the past dozen years, great progress has been made in developing highly efficient homogenous gold...
A novel gold-catalyzed water-mediated carbene cascade reaction of propargyl diazoacetates has been d...
Since earlier work on the use of arenediazonium tetrafluoroborates under gold-photoredox co-catalyze...
Historically, chemists have been motivated by problems in total synthesis or by a desire to develop ...
In recent years, gold(I) complexes have seen increased use as catalysts for the activation of alkyne...
A facile gold-catalyzed oxidation terminal alkynes to synthesize substituted dihydronaphthalen-2(1<...
Gold-catalyzed intramolecular oxidation of terminal alkynes with an arenesulfinyl group as the tethe...
For the past dozen years, homogeneous gold catalysis has evolved from a little known topic in organi...
F or the past dozen years, homogeneous gold catalysis has evolved from a little known topic in organ...
Donor-substituted acyl gold carbenes are challenging to access selectively by gold-promoted intermol...
In the presence of a gold catalyst an unprecedented oxidative cyclization of diynes takes place. The...
Inductive perturbations of C-C triple bonds are shown to dictate the regiochemistry of gold-catalyze...
Alkynes and allenes are one of the most readily available starting materials having ??-bonds. Electr...
The iodination of terminal alkynes for the synthesis of 1-iodoalkynes using N-iodosuccinimide in the...
Recent years have witnessed a tremendous growth in the number of gold-catalyzed highly selective che...
In the past dozen years, great progress has been made in developing highly efficient homogenous gold...
A novel gold-catalyzed water-mediated carbene cascade reaction of propargyl diazoacetates has been d...
Since earlier work on the use of arenediazonium tetrafluoroborates under gold-photoredox co-catalyze...
Historically, chemists have been motivated by problems in total synthesis or by a desire to develop ...
In recent years, gold(I) complexes have seen increased use as catalysts for the activation of alkyne...
A facile gold-catalyzed oxidation terminal alkynes to synthesize substituted dihydronaphthalen-2(1<...
Gold-catalyzed intramolecular oxidation of terminal alkynes with an arenesulfinyl group as the tethe...