Aniontova polymerizace akrylovych a methakrylovych esteru v pritomnosti tert-alkoxidu alkalickych kovu.

The thesis is devoted to the controlled anionic polymerization of polar vinyl monomers, namely esters of acrylic and methacrylic acids, using the method of ligated anionic polymerization, the principle of which has been originally developed by the Prague group almost forty years ago. The process utilizes the stabilizing activity of some organometallic compounds which, when added into a polymerization system, restrict distinctly the extent of side reactions. Except for low-temperature methacrylate polymerizations, the method was the first successful attempt to polymerize (meth)acrylates in a controlled way. In the recent 12-15 years, novel types of stabilizing ligands have been designed. The thesis is based on the study and development of initiating systems utilizable for controlled polymerization of (meth)acrylates and styrene. Some of the prepared products were successfully tested as efficient thin polymer film stabilizers at the Department of Materials Science and Engineering, University of Pennsylvania.The 2nd vol. is in English.Available from STL Prague, CZ / NTK - National Technical LibrarySIGLECZCzech Republi