STUDY OF KINETICS AND OXIDATION MECHANISM OF ALCOHOLS BY PALLADIUM (II) TETRAAQUACOMPLEX

The aim is to determine the basic kinetic regularities and oxidation reaction processing mechanism of the alifatic alconols C*001 - C*004 and benzilic alcohol by a palladium tetraaquacomplex. The general law of the reaction proceeding rate at oxidation of the alcohols by palladium (II) tetraaquacomplex has been specified. The basic routes have been shown, on one of them the oxidation proceeds with participation of the colloid Pd(O) forming during alcohol oxidation. It has been proven in experiment that the investigated reactions proceed through the stage of forming the intermediate compound containing the palladium-carbon bond. The influence of the gas medium composition on the rate of each route and role of the water in the oxidation of the alcohols by the palladium (II) compounds has been shown. The kinetic regularities and high-selective oxidation conditions of the alcohols by the tetraaquacomplex PD(II) and also a possibility of the catalysis at performing reaction in the molecular oxygen atmosphere have been revealedAvailable from VNTIC / VNTIC - Scientific & Technical Information Centre of RussiaSIGLERURussian Federatio