SPECIAL FEATURES IN ELECTRONIC STRUCTURE OF ORGANIC COMPOUNDS OF SILICON AND SULPHUR ACCORDING TO DATA OF X-RAY FLUORESCENT SPECTROSCOPY

The work covers the organic compounds of the silicon and sulphur and complexes of the tin chloride and aluminium bromide with organic compounds of the sulphur and phosphorus. The effective charges in a number of the organic compounds of silicon, sulphur and chlorine have been determined firstly by means of the X-ray fluorescent spectroscopy method, at complexing the charges have been re-distributed. The investigation results can be used for forecasting of the reactibility of the silicon and sulphur compounds and also complexing mechanisms. The methods of the internal spectral standard for X-ray spectra have been developed. The correlation dependences between charge values and chemical drifts of the X-ray lines have been foundAvailable from VNTIC / VNTIC - Scientific & Technical Information Centre of RussiaSIGLERURussian Federatio