ORHANOLANTHANIDES. COMPLEXES WITH BRIDGE NAPHTHALENE LIGAND

The work covers the organic and hetero-organic compounds of rare-earth metals. The aim is to synthesize the complexes of the lanthanides with naphthalene and naphthalene-containing ligands, to study their structures and properties, to elucidate the character of lanthanide-naphthalene interaction. The binuclear complexes of lanthanum (III) and europium (II) with bridge naphthalene dianion have been made firstly and characterized. The rare-earth element compounds containing the lanthanide - aren - transition metal group have been made firstly and investigated. The synthesis methods of the new naphthalene cpmplexes of rare-earth elemenrs have been developed, a principial possibility to use them for making new organolanthanides has been shown. The work results can be used in the Institute of Hetero-Organic Compounds (Russian Academy of Sciences), Institute of General and Non-Organic Chemistry (Russian Academy of Sciences), Moscow University, Research Physical-Chemical InstituteAvailable from VNTIC / VNTIC - Scientific & Technical Information Centre of RussiaSIGLERURussian Federatio