Topics
methyl isobutyl ketoneChemical substance
MIBKChemical substance
acetoneChemical substance
acidChemical compound
Three contrasting classes of solid acid-base materials have been impregnated with palladium to produce active multifunctional catalysts for the one-step conversion of acetone to methyl isobutyl ketone (MIBK), an industrially important solvent. The Pd supported heteropolyacid, Pd/Cs2.5Ho.5PWi204o (Pd/Cs2.5PW), known to possess Bronsted acid sites high in strength, was tested in both liquid phase and gas phase reaction conditions [1]. The Pd/Cs2.5PW catalysts with low Pd concentration proved to be significantly more active in the liquid phase with a Pd loading of 0.1 wt% proving to be sufficient to give acetone conversions of up to 55% at over 90% MIBK selectivity, achieved at a temperature range of 180-200 °C. 1.EThOS - Electronic Theses Onl...
Highly efficient catalyst systems were developed that allow the palladium-catalyzed cross-coupling o...
An organic-inorganic hybrid material, PK-SiO2 (PK = polyketone), was employed as support for Pd cata...
Pd-doped propyl sulfonic acid-functionalized hollow nanospheres proved to be efficient bifunctionali...
Four catalyst systems, Pd-KOH/silica, Pd-CsOH/silica, Ni-KOH/silica, and Ni-CsOH/silica, have been i...
Novel layered double hydroxides, [MAl4(OH)12](NO3)2·nH2O (M = (Li+)2, Co2+, Ni2+, Cu2+, Zn2+), impre...
Generally, metal nanoparticles catalysts are prepared in the presence of a stabilizing agent in orde...
The catalytic hydrogenation of acetone is an important area of catalytic process to produce fine che...
The synthesis of methyl isobutyl ketone (MIBK) can be carried out by the condensation of acetone in ...
For the first time, polyketone (poly-3-oxotrimethylene, PK) has been employed as support for Pd nano...
Palladium acetate catalysed the oxidation of primary and secondary alcohols to aldehydes and ketones...
The main aim of this thesis was studied the niobium oxide promoting effect on Pd/A^Os catalyst at me...
The kinetics of one-step synthesis of methyl isobutyl ketone from acetone was studied in the presenc...
The investigations for more environmentally benign solid base catalysts have increased significantly...
Generally, metal nanoparticles catalysts are prepared in the presence of a stabilizing agents in ord...
The synthesis of dimethyl acetals of carbonyl compounds such as cyclohexanone, acetophenone, and ben...
Highly efficient catalyst systems were developed that allow the palladium-catalyzed cross-coupling o...
An organic-inorganic hybrid material, PK-SiO2 (PK = polyketone), was employed as support for Pd cata...
Pd-doped propyl sulfonic acid-functionalized hollow nanospheres proved to be efficient bifunctionali...
Four catalyst systems, Pd-KOH/silica, Pd-CsOH/silica, Ni-KOH/silica, and Ni-CsOH/silica, have been i...
Novel layered double hydroxides, [MAl4(OH)12](NO3)2·nH2O (M = (Li+)2, Co2+, Ni2+, Cu2+, Zn2+), impre...
Generally, metal nanoparticles catalysts are prepared in the presence of a stabilizing agent in orde...
The catalytic hydrogenation of acetone is an important area of catalytic process to produce fine che...
The synthesis of methyl isobutyl ketone (MIBK) can be carried out by the condensation of acetone in ...
For the first time, polyketone (poly-3-oxotrimethylene, PK) has been employed as support for Pd nano...
Palladium acetate catalysed the oxidation of primary and secondary alcohols to aldehydes and ketones...
The main aim of this thesis was studied the niobium oxide promoting effect on Pd/A^Os catalyst at me...
The kinetics of one-step synthesis of methyl isobutyl ketone from acetone was studied in the presenc...
The investigations for more environmentally benign solid base catalysts have increased significantly...
Generally, metal nanoparticles catalysts are prepared in the presence of a stabilizing agents in ord...
The synthesis of dimethyl acetals of carbonyl compounds such as cyclohexanone, acetophenone, and ben...
Highly efficient catalyst systems were developed that allow the palladium-catalyzed cross-coupling o...
An organic-inorganic hybrid material, PK-SiO2 (PK = polyketone), was employed as support for Pd cata...
Pd-doped propyl sulfonic acid-functionalized hollow nanospheres proved to be efficient bifunctionali...
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