New system technologies are continuously improving the performance of vehicles with regard to safety, comfort, stability and the environment. The development of control systems based on anti-lock braking system, active steering control, adaptive cruise control, collision avoidance, electronic stability programme or roll-over prevention systems, facilitated these improvements. In order to maximise the benefits from such devices, information about the tyre/road friction parameter is required in real-time. As it is impractical to measure the tyre/road friction coefficient, estimation from other available parameters is essential. In this thesis, the main theoretical contribution is the development of sliding mode schemes for tyre/road friction ...