Add to ORKGThe synthesis and characterisation of a range of ligands capable of binding four or five transition metals has been explored in an attempt to synthesise a model for the oxygen evolving centre of photosystem II. Difficulty was encountered in isolating the pure, deprotected ligands. A ligand based on 1,4,7-triazacyclononane containing three alcohol donors was isolated, investigated and compared against similar ligands. A series of copper N-oxide Bis(N,N'-Disalicylalethylenediamine) derivatives were synthesised and fully characterised. The electron paramagnetic resonance spectra (EPR) of these complexes were measured and compared in order to determine the relative Lewis acidity of the central metal. Electron nuclear double resonance (ENDOR) sp...
Electron Nuclear DOuble Resonance (ENDOR) spectroscopy has been employed in this Thesis to study a r...
Second coordination sphere interactions of metal centres involving hydrogen bonding, ion-pairing or ...
This thesis describes the synthesis of a series of mixed N,0,S donor ligands, their co-ordination ch...
The synthesis and characterisation of a range of ligands capable of binding four or five transition ...
The synthesis and characterisation of a range of ligands capable of binding four or five transition ...
The synthesis and characterisation of a range of ligands capable of binding four or five transition ...
Color poster with text, images, diagrams, and graphs.Dioxygenase enzymes catalyze critical reactions...
The thesis begins with an introduction to salen complexes describing possible types of co-ordination...
Six Group 4 metallocene derivatives of group 4 incorporating a redox active benzene-1,2-thiolate lig...
Six Group 4 metallocene derivatives of group 4 incorporating a redox active benzene-1,2-thiolate lig...
The investigation has consisted of two elements, one concentrating on the stabilities of metal compl...
This undergraduate thesis was submitted In partial fulfillment of the requirements for the degree of...
This undergraduate thesis was submitted In partial fulfillment of the requirements for the degree of...
This thesis describes the design, synthesis and reactivity of bimetallic complexes of doubly-pillar...
There are twenty four elements known to be necessary for human life, seven of which are transition m...
Electron Nuclear DOuble Resonance (ENDOR) spectroscopy has been employed in this Thesis to study a r...
Second coordination sphere interactions of metal centres involving hydrogen bonding, ion-pairing or ...
This thesis describes the synthesis of a series of mixed N,0,S donor ligands, their co-ordination ch...
The synthesis and characterisation of a range of ligands capable of binding four or five transition ...
The synthesis and characterisation of a range of ligands capable of binding four or five transition ...
The synthesis and characterisation of a range of ligands capable of binding four or five transition ...
Color poster with text, images, diagrams, and graphs.Dioxygenase enzymes catalyze critical reactions...
The thesis begins with an introduction to salen complexes describing possible types of co-ordination...
Six Group 4 metallocene derivatives of group 4 incorporating a redox active benzene-1,2-thiolate lig...
Six Group 4 metallocene derivatives of group 4 incorporating a redox active benzene-1,2-thiolate lig...
The investigation has consisted of two elements, one concentrating on the stabilities of metal compl...
This undergraduate thesis was submitted In partial fulfillment of the requirements for the degree of...
This undergraduate thesis was submitted In partial fulfillment of the requirements for the degree of...
This thesis describes the design, synthesis and reactivity of bimetallic complexes of doubly-pillar...
There are twenty four elements known to be necessary for human life, seven of which are transition m...
Electron Nuclear DOuble Resonance (ENDOR) spectroscopy has been employed in this Thesis to study a r...
Second coordination sphere interactions of metal centres involving hydrogen bonding, ion-pairing or ...
This thesis describes the synthesis of a series of mixed N,0,S donor ligands, their co-ordination ch...