International audienceThe gas-phase interactions between Ca2+ and cysteine (Cys) have been investigated through the use of electrospray ionization/mass spectrometry techniques and B3LYP/6-311++G(3df,2p)//B3LYP/6-311+G(d,p) density functional theory computations. The unimolecular collision-activated decomposition of [Ca(Cys)]2+ is dominated by the loss of ammonia, a Coulomb explosion yielding NH4+ and [CaC3H3O2S]+, and the loss of H2S. The detection of lighter [C3H3OS]+ monocations indicates that the [CaC3H4O2S]2+ doubly charged species produced by the loss of ammonia undergo a subsequent Coulomb explosion yielding [C3H3OS]++CaOH+. This [C3H3OS]+ cation finally decomposes into [C2H3S]++CO. Alternatively, the aforementioned [CaC3H4O2S]2+ dica...
International audienceThe gas-phase reactions between Ca2+ and thiourea are investigated by means of...
International audienceLow-energy collision-induced dissociation (CID) of deprotonated l-cysteine S-s...
International audienceThe gas-phase reactions between Ca2+ and thiourea are investigated by means of...
International audienceThe gas-phase interactions between Ca2+ and cysteine (Cys) have been investiga...
The gas‐phase interactions between Ca2+ and cysteine (Cys) have been investigated through the use of...
International audienceThe gas‐phase reactions between Ca2+ and glycine ([Ca(gly)]2+) have been inves...
International audienceThe gas‐phase reactions between Ca2+ and glycine ([Ca(gly)]2+) have been inves...
International audienceThe collision induced dissociation of formamide–Ca2+ complexes produced in the...
International audienceThe electronebulization of a cobalt(II)/cysteine(Cys) mixture in water/methano...
International audienceThe gas-phase interactions of cysteine with di-organotin and tri-organotin com...
The gas-phase reactions between urea and Ca2+ have been investigated by means of electrospray mass s...
The gas-phase reactions between urea and Ca 2+ have been investigated by means of electrospray mass ...
International audienceThe gas-phase reactions between Ca2+ and thiourea are investigated by means of...
International audienceLow-energy collision-induced dissociation (CID) of deprotonated l-cysteine S-s...
International audienceThe gas-phase reactions between Ca2+ and thiourea are investigated by means of...
International audienceThe gas-phase interactions between Ca2+ and cysteine (Cys) have been investiga...
The gas‐phase interactions between Ca2+ and cysteine (Cys) have been investigated through the use of...
International audienceThe gas‐phase reactions between Ca2+ and glycine ([Ca(gly)]2+) have been inves...
International audienceThe gas‐phase reactions between Ca2+ and glycine ([Ca(gly)]2+) have been inves...
International audienceThe collision induced dissociation of formamide–Ca2+ complexes produced in the...
International audienceThe electronebulization of a cobalt(II)/cysteine(Cys) mixture in water/methano...
International audienceThe gas-phase interactions of cysteine with di-organotin and tri-organotin com...
The gas-phase reactions between urea and Ca2+ have been investigated by means of electrospray mass s...
The gas-phase reactions between urea and Ca 2+ have been investigated by means of electrospray mass ...
International audienceThe gas-phase reactions between Ca2+ and thiourea are investigated by means of...
International audienceLow-energy collision-induced dissociation (CID) of deprotonated l-cysteine S-s...
International audienceThe gas-phase reactions between Ca2+ and thiourea are investigated by means of...