Volcanic ash as a sustainable binder material: an extensive review

The construction industry is affected by the constant growth of populations in urban areas. The demands for cement production has an increasing environmental impact, and there are urgent demands for alternative sustainable solutions. Volcanic ash (VA) is an abundant low cost mate-rial that, because of its chemical composition and amorphous atomic structure, has been consid-ered as a suitable material to replace Portland cement clinker for use as a binder in cement pro-duction. Over the last decade, there has been interest in using alkali-activated VA material as an alternative material to replace ordinary Portland cement. In this way, a valuable product may be derived from a currently under-utilized material. Additionally, alkali-activated VA-based mate-rials may be suitable for building applications because of their good densification behaviour, mechanical properties and low porosity. This article describes the most relevant findings from researchers around the world on the role of the chemical composition and mineral contents of VA on the reactivity during the alkali-activation reaction; the effect of synthesis factors, which include the concentration of the alkaline activator, the solution-to-binder ratio and the curing conditions, on the properties of alkali-activated VA-based materials; and the mechanical per-formance and durability properties of these materials.This research is sponsored by the National Secretary of Higher Education Science Technology and Innovation of Ecuador (SENESCYT).Peer ReviewedPostprint (published version