Stereoselective Allylic Alkylations of Amino Ketones and Their Application in the Synthesis of Highly Functionalized Piperidines

Prudel, Cynthia
Huwig, Kai
Kazmaier, Uli

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Publication date

January 2020

DOI

10.22028/D291-33244

Publisher

Saarländische Universitäts- und Landesbibliothek

Journal

Chemistry - A European Journal

Language

English

Abstract

Chelated ketone enolates are excellent nucleophiles for allylic alkylations. Electron-withdrawing groups on the allyl moiety allow subsequent intramolecular Michael additions giving rise to piperidines with up to five stereogenic centers

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Stereoselective Allylic Alkylations of Amino Ketones and Their Application in the Synthesis of Highly Functionalized Piperidines

Abstract

Extracted data

Stereoselective Allylic Alkylations of Amino Ketones and Their Application in the Synthesis of Highly Functionalized Piperidines

Abstract

Extracted data

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