Treatment of hematoporphyrin IX dimethyl ester (7) with tetrapropylammonium perruthenate (Prn4N)(Ru04) and N-methylmorpholine N-oxide affords a high yield of the separable monoacetylmono(1-hydroxyethyl)-deuteroporphyrin isomers 5 and 6. Proton NMR NOE experiments and chemical transformations involving specific individual deuteration at the 1- and 3-methyls and 2- and 4-vinyls are used to characterize the isomers. © 1990, American Chemical Society. All rights reserved
Treatment of protoporphyrin-IX, deuteroporphyrin-IX, 2,4- diacetyldeuteroporphyrin-IX, and mesoporph...
Herein, we report the functionalization of the β-positions of deutero- and protoporphyrin IX dimethy...
The aim is to synthesize the Fe-octaphenyl tetraazaporphyrin, to study its physical-chemical propert...
Using commercially available hemin (5) as the starting material, routes for preparation of monovinyl...
Treatment of zinc(II) deuteroporphyrin-IX dimethyl ester with thallium(III) trifluoroacetate, follow...
In connection with proposed 19F NMR studies of reconstituted fluorine-substituted heme proteins, syn...
This study describes the partial synthesis of porphyrin SA11 (la) from protoporphyrin IX DME (32). C...
Total syntheses, from monopyrroles via tripyrrenes and a,c-biladienes, of the four isomers 2–5 of pr...
In order to settle the precise identity of certain resonances in the paramagnetic n.m.r. spectra of ...
A new total synthesis of a protoporphyrin IX derivative in which the α-methylene protons of the 13,1...
Bibliography: leaves 227-238vii, 238 leaves : ill. (some col.) ; 30 cm.Thesis (Ph.D.)--University of...
In order to aid in elucidation of the structure of the active components in hematoporphyrin derivati...
Tetraphenylporphine (TPP) and its para-methyl derivative have been synthesized by direct reaction o...
Porphyrin dimers 9 with ether linkages and possible isomers bis[l-[6,7-bis[2-(methoxycarbonyl)ethyl]...
Zinc(II) porphyrins bearing unsubstituted β positions can be mercurated at the β position and at an ...
Treatment of protoporphyrin-IX, deuteroporphyrin-IX, 2,4- diacetyldeuteroporphyrin-IX, and mesoporph...
Herein, we report the functionalization of the β-positions of deutero- and protoporphyrin IX dimethy...
The aim is to synthesize the Fe-octaphenyl tetraazaporphyrin, to study its physical-chemical propert...
Using commercially available hemin (5) as the starting material, routes for preparation of monovinyl...
Treatment of zinc(II) deuteroporphyrin-IX dimethyl ester with thallium(III) trifluoroacetate, follow...
In connection with proposed 19F NMR studies of reconstituted fluorine-substituted heme proteins, syn...
This study describes the partial synthesis of porphyrin SA11 (la) from protoporphyrin IX DME (32). C...
Total syntheses, from monopyrroles via tripyrrenes and a,c-biladienes, of the four isomers 2–5 of pr...
In order to settle the precise identity of certain resonances in the paramagnetic n.m.r. spectra of ...
A new total synthesis of a protoporphyrin IX derivative in which the α-methylene protons of the 13,1...
Bibliography: leaves 227-238vii, 238 leaves : ill. (some col.) ; 30 cm.Thesis (Ph.D.)--University of...
In order to aid in elucidation of the structure of the active components in hematoporphyrin derivati...
Tetraphenylporphine (TPP) and its para-methyl derivative have been synthesized by direct reaction o...
Porphyrin dimers 9 with ether linkages and possible isomers bis[l-[6,7-bis[2-(methoxycarbonyl)ethyl]...
Zinc(II) porphyrins bearing unsubstituted β positions can be mercurated at the β position and at an ...
Treatment of protoporphyrin-IX, deuteroporphyrin-IX, 2,4- diacetyldeuteroporphyrin-IX, and mesoporph...
Herein, we report the functionalization of the β-positions of deutero- and protoporphyrin IX dimethy...
The aim is to synthesize the Fe-octaphenyl tetraazaporphyrin, to study its physical-chemical propert...