Add to ORKGThe two-electron mixed-valent complex Rh20, II(tfepma)2(CNtBu)2Cl2 (tfepma = CH3N[P(OCH2CF3)2]2) photocatalytically splits HCl to generate H2. Whereas this catalyst degrades rapidly, with H2 production ceasing after about 36 hours (3 turnovers), a modified complex, Rh20, II(tfepma)2(CNAd)2Cl2 (CNAd = 1-adamantylisocyanide) displays enhanced stability with sustained H2 production continuing for \u3e144 h (7 turnovers).© 2012 The Royal Society of Chemistry
The development of multicomponent molecular systems for the photocatalytic reduction of water to hyd...
Detailed studies on hydrogen evolution by decamethylruthenocene ([Cp*2RuII]) highlighted that metall...
International audienceMolecular hydrogen (H2) is considered one of the most promising fuels to decar...
Two dirhodium(II) complexes, [Rh<sup>II</sup><sub>2</sub>(μ-O<sub>2</sub>CCH<sub>3</sub>)<sub>2</su...
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2001.Vita.Includes bibli...
The photocatalytic generation of hydrogen (H2) from protons by two cyclometalated ruthenium–platinum...
The photocatalytic generation of hydrogen (H2) from protons by two cyclometalated ruthenium-platinum...
Catalytically evolving hydrogen from a system that photosensitizes diiron hydrogenase could be a car...
The contrasting early-time photodynamics of two related Ru/Pt photocatalysts with very different pho...
Two-electron mixed-valence compounds promote the rearrangement of the two-electron bond photochemica...
Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2003.Vita.Includes bibliog...
We present an artificial photocatalytic model for photosystem I (PSI) using [ReBr(CO)3bipy)] (1) as ...
© 2020 American Chemical Society. A single molecular rhodium catalyst system (PC2-Cp#RhIII) bearing ...
We report a very efficient homogeneous system for the visible-light-driven hydrogen production in pu...
Concerns over increasing global energy demands, finite fossil fuel reserves, and climate change have...
The development of multicomponent molecular systems for the photocatalytic reduction of water to hyd...
Detailed studies on hydrogen evolution by decamethylruthenocene ([Cp*2RuII]) highlighted that metall...
International audienceMolecular hydrogen (H2) is considered one of the most promising fuels to decar...
Two dirhodium(II) complexes, [Rh<sup>II</sup><sub>2</sub>(μ-O<sub>2</sub>CCH<sub>3</sub>)<sub>2</su...
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2001.Vita.Includes bibli...
The photocatalytic generation of hydrogen (H2) from protons by two cyclometalated ruthenium–platinum...
The photocatalytic generation of hydrogen (H2) from protons by two cyclometalated ruthenium-platinum...
Catalytically evolving hydrogen from a system that photosensitizes diiron hydrogenase could be a car...
The contrasting early-time photodynamics of two related Ru/Pt photocatalysts with very different pho...
Two-electron mixed-valence compounds promote the rearrangement of the two-electron bond photochemica...
Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2003.Vita.Includes bibliog...
We present an artificial photocatalytic model for photosystem I (PSI) using [ReBr(CO)3bipy)] (1) as ...
© 2020 American Chemical Society. A single molecular rhodium catalyst system (PC2-Cp#RhIII) bearing ...
We report a very efficient homogeneous system for the visible-light-driven hydrogen production in pu...
Concerns over increasing global energy demands, finite fossil fuel reserves, and climate change have...
The development of multicomponent molecular systems for the photocatalytic reduction of water to hyd...
Detailed studies on hydrogen evolution by decamethylruthenocene ([Cp*2RuII]) highlighted that metall...
International audienceMolecular hydrogen (H2) is considered one of the most promising fuels to decar...