Modern conditions and recent environmental development of the Muskiz estuary: historical disturbance by the largest oil refinery of Spain

In 1970 the largest oil refinery in Spain was built on the Muskiz estuary and occupies most of its original surface. An integrated high-resolution microfaunal-geochemical study has revealed the evolution and environmental development of this estuary during the last 120 years, mainly by the identification and assessment of natural processes versus anthropogenic impacts. Benthic foraminifera, trace elements and PAHs data from surface sediment samples and sediment cores from the meagre remaining intertidal flat and marsh areas together with short-life radiometric isotope determinations provide a chronology for environmental changes in this estuary. Concentrations of organic and inorganic pollutant, both in modern and recent materials, are generally low and show no significative variations in space or time, except those associated to sedimentological changes in the core records. Natural processes in the middle estuary indicate the change from previous sandy, normal-salinity conditions to a muddy brackish environment around 1914. Anthropogenic impacts are not related to persistent historical pollution on this estuary but merely to the occupation of the estuary and the elimination of its different original ecosystems, so causing a general impoverishment of its environmental quality.En 1970 se construyó en la Ría de Muskiz la mayor refinería de petróleo de España ocupando la mayor parte de los dominios estuarinos originales. Este trabajo utiliza un enfoque integrado geoquímico-micropaleontológico de alta resolución con el fin de examinar la evolución estuarina y el desarrollo ambiental de esta zona costera durante los últimos 120 años, distinguiendo particularmente entre los procesos naturales e impactos antrópicos. Se analizaron foraminíferos bentónicos, elementos traza e hidrocarburo