We present ALMA 3 mm molecular line and continuum observations with a resolution of ∼3.5 arcsec towards five first hydrostatic core (FHSC) candidates (L1451-mm, Per-bolo 58, Per-bolo 45, L1448-IRS2E, and Cha-MMS1). Our goal is to characterize their envelopes and identify the most promising sources that could be bona fide FHSCs. We identify two candidates that are consistent with an extremely young evolutionary state (L1451-mm and Cha-MMS1), with L1451-mm being the most promising FHSC candidate. Although our envelope observations cannot rule out Cha-MMS1 as an FHSC yet, the properties of its CO outflow and SED published in recent studies are in better agreement with the predictions for a young protostar. For the remaining three sources, our ...