The synthesis and electronic structures of the square-planar high-spin FeII complexes (MesPDPPh)Fe(OEt2) and (MesPDPPh)Fe(thf) were investigated. Analysis of these compounds using a combination of 1H NMR and 57Fe Mössbauer spectroscopies, in conjunction with computational analysis, has resulted in a rationalization for their unusual electronic structures, which arise from the unique coordination environment enforced by the pyridine dipyrrolide chelate ligand. The reactivity of (MesPDPPh)Fe(thf) with organic azides has been probed and resulted in the isolation of an array of products that are consistent with the generation of reactive iron nitrene intermediates. Computational analysis has evidenced that the suspected iron nitrene species are...
International audienceNitrene transfer reactions have emerged as one of the most powerful and versat...
International audienceNitrene transfer reactions have emerged as one of the most powerful and versat...
Iron terminal imido species are typically implicated as reaction intermediates in iron catalyzed tra...
A sterically accessible tert-butyl-substituted dipyrrinato di-iron(II) complex [(tBuL)FeCl]2 possess...
The dipyrrinato iron catalyst reacts with organic azides to generate a reactive, high-spin imido rad...
Imidyl and nitrene metal species play an important role in the N-functionalisation of unreactive C–H...
International audienceNitrene transfer reactions to various hydrocarbon molecules can be efficiently...
International audienceNitrene transfer reactions to various hydrocarbon molecules can be efficiently...
International audienceNitrene transfer reactions to various hydrocarbon molecules can be efficiently...
International audienceNitrene transfer reactions to various hydrocarbon molecules can be efficiently...
Imidyl and nitrene metal species play an important role in the N-functionalisation of unreactive C–H...
The factors that enable intermolecular C–H amination by iron complexes supported by dipyrromethene l...
Iron terminal imido species are typically implicated as reaction intermediates in iron-catalyzed tra...
International audienceNitrene transfer reactions have emerged as one of the most powerful and versat...
International audienceNitrene transfer reactions have emerged as one of the most powerful and versat...
International audienceNitrene transfer reactions have emerged as one of the most powerful and versat...
International audienceNitrene transfer reactions have emerged as one of the most powerful and versat...
Iron terminal imido species are typically implicated as reaction intermediates in iron catalyzed tra...
A sterically accessible tert-butyl-substituted dipyrrinato di-iron(II) complex [(tBuL)FeCl]2 possess...
The dipyrrinato iron catalyst reacts with organic azides to generate a reactive, high-spin imido rad...
Imidyl and nitrene metal species play an important role in the N-functionalisation of unreactive C–H...
International audienceNitrene transfer reactions to various hydrocarbon molecules can be efficiently...
International audienceNitrene transfer reactions to various hydrocarbon molecules can be efficiently...
International audienceNitrene transfer reactions to various hydrocarbon molecules can be efficiently...
International audienceNitrene transfer reactions to various hydrocarbon molecules can be efficiently...
Imidyl and nitrene metal species play an important role in the N-functionalisation of unreactive C–H...
The factors that enable intermolecular C–H amination by iron complexes supported by dipyrromethene l...
Iron terminal imido species are typically implicated as reaction intermediates in iron-catalyzed tra...
International audienceNitrene transfer reactions have emerged as one of the most powerful and versat...
International audienceNitrene transfer reactions have emerged as one of the most powerful and versat...
International audienceNitrene transfer reactions have emerged as one of the most powerful and versat...
International audienceNitrene transfer reactions have emerged as one of the most powerful and versat...
Iron terminal imido species are typically implicated as reaction intermediates in iron catalyzed tra...