Kinetic applications of electron paramagnetic resonance spectroscopy. 27. Isomerization of cyclopropylcarbinyl to allylcarbinyl

Maillard, B.
Forrest, D.
Ingold, K. U.

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Publication date

January 1976

DOI

10.1021/ja00438a047

ISSN

0002-7863

Citation count (estimate)

147

Abstract

The rate constant for isomerization of cyclopropylcarbinyl to allylcarbinyl has been measured by EPR spectroscopy. It can be represented by: log(ki/s-1) = (12.48 \ub1 0.85) - (5.94 \ub1 0.57)/\u3b8, where \u3b8 = 2.3RT kcal/mol. This reaction is compared with other primary alkyl radical isomerizations.Peer reviewed: YesNRC publication: Ye

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Kinetic applications of electron paramagnetic resonance spectroscopy. 27. Isomerization of cyclopropylcarbinyl to allylcarbinyl

Abstract

Extracted data

Kinetic applications of electron paramagnetic resonance spectroscopy. 27. Isomerization of cyclopropylcarbinyl to allylcarbinyl

Abstract

Extracted data

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