Surface photochemistry: generation of benzyl radical pairs on dry silica gel

Singlet and triplet benzyl radical pairs have been generated on silica gel by photolysis of a benzyl phenylacetate, a dibenzyl ketone, and a dibenzyl sulfone. The extent of geminate radical recombination has been measured and requires that translational motion of radicals occur on the silica gel surface. This motion was affected by the radical pair multiplicity and the photolysis temperature, but was relatively insensitive to the state of hydration of the silica gel and the presence of coadsorbates. The presence of certain rearranged starting materials, which are not formed in solution, amongst the products from photolysis of both dibenzyl ketone and dibenzyl sulfone on silica gel indicates the restrictions on radical movement on the surface on the shorter timescale of the benzyl\ufffdphenylacetyl and benzyl \ufffd benzyl sulfonyl radical pairs.NRC publication: Ye