Photochemistry of 1-benzoyl-2,2-dialkylcyclopropanes. Importance of conformational effects on biradical lifetimes

Johnston, Linda J.
Scaiano, J. C.
Sheppard, J. W.
Bays, J. P.

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Publication date

March 1986

DOI

10.1016/0009-2614(86)85062-X

ISSN

0009-2614

Abstract

Conformationally locked 1,4-biradicals generated in the Norrish type II reaction of 1-benzoyl-2,2-diethylcyclopropane have lifetimes of 22?4 ns. This lifetime is much shorter than those observed for conformationally mobile biradicals; the difference is attributed to increased end-to-end interaction.NRC publication: Ye

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Photochemistry of 1-benzoyl-2,2-dialkylcyclopropanes. Importance of conformational effects on biradical lifetimes

Abstract

Extracted data

Photochemistry of 1-benzoyl-2,2-dialkylcyclopropanes. Importance of conformational effects on biradical lifetimes

Abstract

Extracted data

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