Two helices from one chiral centre – self organization of disc shaped chiral nanoparticles

Gold nanoparticles (AuNPs) have been prepared and surfacefunctionalizedwith a mixture of 1-hexanethiol co-ligands and chiraldiscogen ligands separated from a disulfide function via a flexiblespacer. Polarized optical microscopy together with differentialscanning calorimetry showed that the organic corona of thenanocomposite forms a stable chiral discotic nematic (ND*) phasewith a wide thermal range. Synchrotron X-ray diffraction showedthat gold NPs form a superlattice with p2 plane symmetry. Analysisindicated that the corona takes up the shape of a flexiblemacrodisk. Synchrotron radiation-based circular dichroism signalsof thin films are significantly enhanced on the isotropic-LCtransition in line with the formation of a chiral nematic phase of theorganic corona. At lower temperatures the appearance of CDsignals associated with the NPs is indicative of the formation of asecond helical structure. The decreased volume required and thechiral environment of the disc ligands drives the nanoparticles intocolumns that arrange helically parallel to the shortest axis of thetwo dimensional lattice