Treatment of Cu(NO3)2 with 1,1′-bis(diphenylphosphino)ferrocene (dppf) gave [{Cu(μ-NO3-O)(dppf-P,P′)}2] which readily exchanged with NaO2CH or KI to give [{Cu(μ-O2CH-O,O′)(dppf-P,P′)}2] or [{Cu(μ-I)(dppf-P,P′)}2]. X-Ray structural analysis of the complexes revealed three tetrahedral copper(I) dimers with nitrate, iodide or formate preferentially in bridging and dppf consistently in chelating modes. The P-Cu-P chelate angle in the nitrate [11 7.8(1)°] is the largest of known dppf chelates in all geometries. These structures are different from their triphenylphosphine analogues which are all monomers. Exchanges of the nitrate complex with other carboxylates gave [{Cu(μ-O2CR)(dppf-P,P′)}n] (R = Me, CF3, Et, Prn or Ph). It also reacted with a s...
International audienceDinuclear copper(I) complexes have been prepared starting from bis(diphenylpho...
Reactions of 2,6-dimethylphenyl phosphate (dmppH2) and 2,6-diisopropylphenyl phosphate (dippH2) with...
Copper(l) complexes of 1,2-bis(diphenylphosphino)ethane (dppe) with a stoichiometry Cu-2(dppe)(3)(X)...
10.1039/DT9940003451Journal of the Chemical Society, Dalton Transactions233451-345
1′-(Diphenylphosphino)-1-cyanoferrocene (<b>3</b>), a new donor-asymmetric ferrocene ligand obtained...
The redox-active diphosphine ligand 1,1′-bis(diphenylphosphino)ferrocene (dppf) has been used to s...
The ligand bis(diphenylphosphino) isopropylamine (dppipa) has been shown to be a versatile ligand sp...
The remarkable stability of [Cu(dppf)(odppf)]BF4 [dppf = 1,1'-bis(diphenylphosphino)ferrocene, odppf...
The co-ordination chemistry of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) with Cu I...
We report the synthesis and structures of three copper(I) complexes, [Cu4(μ3-Cl)2(μ2-Cl)2{μ2-(2,6-Me...
The platinum complex [{PtCl2(C2H4)}2(dpf *) 1 [dpf * = octamethyl-5,5′-di(2-pyridyl)ferrocene] has b...
cited By 66International audienceThe monophosphino-boranes o-iPr2P(C6H 4)BR2 (1: R = Ph and 3: R = C...
A series of dinuclear copper(I)N,C,N-andP,C,P-carbodiphosphorane (CDP) complexes using multidentate ...
The reaction of a series of dinucleating bis(β-diketiminate) pro-ligands with mesitylcopper in the p...
Three different complexes of copper (I) with bridging 1, 2-bis(diphenylphosphino)ethane (dppe), name...
International audienceDinuclear copper(I) complexes have been prepared starting from bis(diphenylpho...
Reactions of 2,6-dimethylphenyl phosphate (dmppH2) and 2,6-diisopropylphenyl phosphate (dippH2) with...
Copper(l) complexes of 1,2-bis(diphenylphosphino)ethane (dppe) with a stoichiometry Cu-2(dppe)(3)(X)...
10.1039/DT9940003451Journal of the Chemical Society, Dalton Transactions233451-345
1′-(Diphenylphosphino)-1-cyanoferrocene (<b>3</b>), a new donor-asymmetric ferrocene ligand obtained...
The redox-active diphosphine ligand 1,1′-bis(diphenylphosphino)ferrocene (dppf) has been used to s...
The ligand bis(diphenylphosphino) isopropylamine (dppipa) has been shown to be a versatile ligand sp...
The remarkable stability of [Cu(dppf)(odppf)]BF4 [dppf = 1,1'-bis(diphenylphosphino)ferrocene, odppf...
The co-ordination chemistry of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) with Cu I...
We report the synthesis and structures of three copper(I) complexes, [Cu4(μ3-Cl)2(μ2-Cl)2{μ2-(2,6-Me...
The platinum complex [{PtCl2(C2H4)}2(dpf *) 1 [dpf * = octamethyl-5,5′-di(2-pyridyl)ferrocene] has b...
cited By 66International audienceThe monophosphino-boranes o-iPr2P(C6H 4)BR2 (1: R = Ph and 3: R = C...
A series of dinuclear copper(I)N,C,N-andP,C,P-carbodiphosphorane (CDP) complexes using multidentate ...
The reaction of a series of dinucleating bis(β-diketiminate) pro-ligands with mesitylcopper in the p...
Three different complexes of copper (I) with bridging 1, 2-bis(diphenylphosphino)ethane (dppe), name...
International audienceDinuclear copper(I) complexes have been prepared starting from bis(diphenylpho...
Reactions of 2,6-dimethylphenyl phosphate (dmppH2) and 2,6-diisopropylphenyl phosphate (dippH2) with...
Copper(l) complexes of 1,2-bis(diphenylphosphino)ethane (dppe) with a stoichiometry Cu-2(dppe)(3)(X)...