UV/Vis absorption spectroscopy (UV/Vis), femtosecond transient absorption spectroscopy (fs-TA), nanosecond transient absorption spectroscopy (ns-TA), and nanosecond time-resolved resonance Raman spectroscopy (ns-TR3), as well as density functional theory (DFT) computations were employed to study the mechanisms and the intermediates in reactions of selected halogenated compounds, including trichloroethylene oxide (TCE oxide), halogenated benzophenones (4-FBP, 4-ClBP, 4-BrBP, 3-FBP, 33’-DFBP, 3-ClBP, 3-BrBP, 2-FBP, 2-ClBP, and 2-BrBP), and halogenated quinoline-based phototriggers (BHQ-OPh and BHQ-OAc). This study investigated the halogen substituent effect on the mechanisms of various water-involved reactions and the influences from the numb...
A combined experimental and theoretical study of the UV photolysis of a typical tetrahalomethane, CB...
The standard one-electron reduction potentials of halogen atoms, E°′(X•/–), and many other radical o...
University of Minnesota Ph.D. dissertation. August 2014. Major: Chemistry. Advisors: Kristopher McNe...
The efficient photosubstitution reaction of <i>m</i>-fluorobenzophenone and the related photohydrati...
Halobenzoquinones (HBQs) are highly toxic disinfection byproducts (DBPs) and are also precursors of ...
Nanosecond time-resolved resonance Raman (ns-TR3) spectroscopy was used in this thesis to study the...
A nanosecond time-resolved resonance Raman (ns-TR 3) spectroscopic investigation of the photoreducti...
The photochemistry of several tribromo-compounds, R−CBr3 (R = CH2OH, CH2OC(O)CF3, COOH) have been st...
Molecular oxygen was used to probe the mechanism of the phototransformation of chlorobenzene and 4-c...
Nanosecond time-resolved resonance Raman (ns-TR3) spectroscopy was employed to investigate the photo...
MSc (Chemistry), North-West University, Mafikeng CampusA theoretical study on the reactions of phlor...
Trichloroethylene oxide is a downstream product in the oxidative metabolism of trichloroethylene (TC...
Chloroperoxidase (CPO) is a potential biocatalyst for use in asymmetric synthesis. The mechanisms of...
The halogenation of monosubstituted benzenes in aqueous solvent was studied using density functional...
In this work we explored the excited state reactivity of triplet chlorobenzenes with density functio...
A combined experimental and theoretical study of the UV photolysis of a typical tetrahalomethane, CB...
The standard one-electron reduction potentials of halogen atoms, E°′(X•/–), and many other radical o...
University of Minnesota Ph.D. dissertation. August 2014. Major: Chemistry. Advisors: Kristopher McNe...
The efficient photosubstitution reaction of <i>m</i>-fluorobenzophenone and the related photohydrati...
Halobenzoquinones (HBQs) are highly toxic disinfection byproducts (DBPs) and are also precursors of ...
Nanosecond time-resolved resonance Raman (ns-TR3) spectroscopy was used in this thesis to study the...
A nanosecond time-resolved resonance Raman (ns-TR 3) spectroscopic investigation of the photoreducti...
The photochemistry of several tribromo-compounds, R−CBr3 (R = CH2OH, CH2OC(O)CF3, COOH) have been st...
Molecular oxygen was used to probe the mechanism of the phototransformation of chlorobenzene and 4-c...
Nanosecond time-resolved resonance Raman (ns-TR3) spectroscopy was employed to investigate the photo...
MSc (Chemistry), North-West University, Mafikeng CampusA theoretical study on the reactions of phlor...
Trichloroethylene oxide is a downstream product in the oxidative metabolism of trichloroethylene (TC...
Chloroperoxidase (CPO) is a potential biocatalyst for use in asymmetric synthesis. The mechanisms of...
The halogenation of monosubstituted benzenes in aqueous solvent was studied using density functional...
In this work we explored the excited state reactivity of triplet chlorobenzenes with density functio...
A combined experimental and theoretical study of the UV photolysis of a typical tetrahalomethane, CB...
The standard one-electron reduction potentials of halogen atoms, E°′(X•/–), and many other radical o...
University of Minnesota Ph.D. dissertation. August 2014. Major: Chemistry. Advisors: Kristopher McNe...