Add to ORKGMethanol is converted to a mixture of hydrocarbons by reaction with zinc iodide at 200 °C with one highly branched alkane, 2,2,3-trimethylbutane (triptane), being obtained in surprisingly high selectivity. Mechanistic studies implicate a two-stage process, the first involving heterogeneously catalyzed formation of a carbon−carbon-bonded species, probably ethylene, that undergoes homogeneously catalyzed sequential cationic methylation to higher hydrocarbons. The first stage can be bypassed by addition of olefins, higher alcohols, or arenes, which act as initiators. Rationales for the particular activity of zinc iodide and for the selectivity to triptane are proposed
After a prolonged effort over many years, the route for the formation of a direct carbon−carbon (C−C...
T he demand for specific fuels and chemical feed-stocks fluctuates, and as a result, logistical mism...
After a prolonged effort over many years, the route for the formation of a direct carbon−carbon (C−C...
Methanol is converted to a mixture of hydrocarbons by reaction with zinc iodide at 200 °C with one h...
Methanol is converted to a mixture of hydrocarbons by reaction with zinc iodide at 200 °C with one h...
Methanol is converted to hydrocarbons by reaction with ZnI2 or InI3 at 200 °C, with surprisingly hig...
Methanol is converted to hydrocarbons by reaction with ZnI2 or InI3 at 200 °C, with surprisingly hig...
The demand for specific fuels and chemical feed-stocks fluctuates, and as a result, logistical misma...
The yield of triptane from the reaction of methanol with zinc iodide is dramatically increased by ad...
13C nuclear magnetic resonance and vapor-phase chromatography have been used to investigate the conv...
InI_3 is able to catalyze the conversion of methanol to a mixture of hydrocarbons at 200 °C with one...
13C nuclear magnetic resonance and vapor-phase chromatography have been used to investigate the conv...
13C nuclear magnetic resonance and vapor-phase chromatography have been used to investigate the conv...
13C nuclear magnetic resonance and vapor-phase chromatography have been used to investigate the conv...
After a prolonged effort over many years, the route for the formation of a direct carbon−carbon (C−C...
After a prolonged effort over many years, the route for the formation of a direct carbon−carbon (C−C...
T he demand for specific fuels and chemical feed-stocks fluctuates, and as a result, logistical mism...
After a prolonged effort over many years, the route for the formation of a direct carbon−carbon (C−C...
Methanol is converted to a mixture of hydrocarbons by reaction with zinc iodide at 200 °C with one h...
Methanol is converted to a mixture of hydrocarbons by reaction with zinc iodide at 200 °C with one h...
Methanol is converted to hydrocarbons by reaction with ZnI2 or InI3 at 200 °C, with surprisingly hig...
Methanol is converted to hydrocarbons by reaction with ZnI2 or InI3 at 200 °C, with surprisingly hig...
The demand for specific fuels and chemical feed-stocks fluctuates, and as a result, logistical misma...
The yield of triptane from the reaction of methanol with zinc iodide is dramatically increased by ad...
13C nuclear magnetic resonance and vapor-phase chromatography have been used to investigate the conv...
InI_3 is able to catalyze the conversion of methanol to a mixture of hydrocarbons at 200 °C with one...
13C nuclear magnetic resonance and vapor-phase chromatography have been used to investigate the conv...
13C nuclear magnetic resonance and vapor-phase chromatography have been used to investigate the conv...
13C nuclear magnetic resonance and vapor-phase chromatography have been used to investigate the conv...
After a prolonged effort over many years, the route for the formation of a direct carbon−carbon (C−C...
After a prolonged effort over many years, the route for the formation of a direct carbon−carbon (C−C...
T he demand for specific fuels and chemical feed-stocks fluctuates, and as a result, logistical mism...
After a prolonged effort over many years, the route for the formation of a direct carbon−carbon (C−C...