Add to ORKGIn the troposphere, the fate of gas-phase Criegee intermediates (CIs) is deemed to be determined by their reactions with water molecules. Here it is shown that CIs produced in situ on the surface of water/acetonitrile (W/AN) solutions react competitively with millimolar carboxylic acids. Present experiments probe, via online electrospray mass spectrometry, CIs’ chemistry on the surface of α-humulene and β-caryophyllene in W/AN microjets exposed to O3(g) for <10 μs. Mass-specific identification lets us establish the progeny of products and intermediates generated in the early stages of CIs’ reactions with H2O, D2O, H218O, and n-alkyl-COOH (n = 1–7). It is found that n-alkyl-COOH competes for CIs with interfacial water, their competitiveness ...
Much is known about OH-radical chemistry in the gas-phase and bulk water. Important atmospheric and ...
Biogenic hydrocarbons emitted by vegetation are important contributors to secondary organic aerosol ...
Secondary organic aerosol (SOA) found in polluted mega-cities contains benzoic acid (BA) as a major ...
In the troposphere, the fate of gas-phase Criegee intermediates (CIs) is deemed to be determined by ...
Levoglucosan (Levo), a C_6-anhydrosaccharide produced in the combustion of cellulosic materials, is ...
The fate of Criegee intermediates (CIs) from the gas-phase ozonolysis of unsaturated organic compoun...
Marine photosynthetic organisms emit organic gases, including the polyolefins isoprene (C_5H_8) and ...
Halogens play key roles in the chemical composition of marine boundary layers, the free troposphere ...
cis-Pinonic acid (CPA), the main product of the atmospheric oxidation of biogenic α-pinene emissions...
We use a large laboratory, modeling, and field dataset to investigate the isoprene + O_3 reaction, w...
A leading source of uncertainty in predicting the climate and health effects of secondary organic ae...
A heterobimetallic VFe complex is demonstrated to catalyse hydrazine disproportionation with yields ...
Numerous field and laboratory studies have shown that amines, especially dimethylamine (DMA), are cr...
The atmospheric oxidation of organic compounds is progressive and leads to the formation of a myriad...
Gas and aqueous phases are essential media for atmospheric chemistry and aerosol formation. Numerous...
Much is known about OH-radical chemistry in the gas-phase and bulk water. Important atmospheric and ...
Biogenic hydrocarbons emitted by vegetation are important contributors to secondary organic aerosol ...
Secondary organic aerosol (SOA) found in polluted mega-cities contains benzoic acid (BA) as a major ...
In the troposphere, the fate of gas-phase Criegee intermediates (CIs) is deemed to be determined by ...
Levoglucosan (Levo), a C_6-anhydrosaccharide produced in the combustion of cellulosic materials, is ...
The fate of Criegee intermediates (CIs) from the gas-phase ozonolysis of unsaturated organic compoun...
Marine photosynthetic organisms emit organic gases, including the polyolefins isoprene (C_5H_8) and ...
Halogens play key roles in the chemical composition of marine boundary layers, the free troposphere ...
cis-Pinonic acid (CPA), the main product of the atmospheric oxidation of biogenic α-pinene emissions...
We use a large laboratory, modeling, and field dataset to investigate the isoprene + O_3 reaction, w...
A leading source of uncertainty in predicting the climate and health effects of secondary organic ae...
A heterobimetallic VFe complex is demonstrated to catalyse hydrazine disproportionation with yields ...
Numerous field and laboratory studies have shown that amines, especially dimethylamine (DMA), are cr...
The atmospheric oxidation of organic compounds is progressive and leads to the formation of a myriad...
Gas and aqueous phases are essential media for atmospheric chemistry and aerosol formation. Numerous...
Much is known about OH-radical chemistry in the gas-phase and bulk water. Important atmospheric and ...
Biogenic hydrocarbons emitted by vegetation are important contributors to secondary organic aerosol ...
Secondary organic aerosol (SOA) found in polluted mega-cities contains benzoic acid (BA) as a major ...