Add to ORKGA set of mild processes for the conversion of vinyl cyclopropyl diazo ketones to highly functionalized cycloheptadienones and vinyl cyclopentenones by use of a target-inspired tandem Wolff/Cope rearrangement sequence is described. A divergent reaction course of the vinyl cyclopropyl diazo ketone substrates under sono- or photochemical activation provides good to excellent yields (55−98%) of the product cycloheptadienones and vinyl cyclopentenones
available in PMC 2014 November 1Highly substituted polycyclic aromatic and heteroaromatic compounds ...
A straightforward total synthesis of the cyclooctenoid sesquiterpene dactylol (1) and of 3a-epi-dact...
As the demand for pharmaceutical agents grow, efficient and cost effective syntheses of these target...
A set of mild processes for the conversion of vinyl cyclopropyl diazo ketones to highly functionaliz...
An investigation of the intramolecular cyclopropanation reactions of α-diazo-β-ketonitriles is repor...
We describe a photo-induced reaction for the in situ generation of highly reactive alkyl diazo compo...
We describe a photo-induced reaction for the in situ generation of highly reactive alkyl diazo compo...
Mild heating of diazo compounds in DMSO furnishes ketone products in moderate to excellent yields. T...
Mild heating of diazo compounds in DMSO furnishes ketone products in moderate to excellent yields. T...
Thesis advisor: Jason S. KingsburyThe research of diazoalkanes dates back more than 100 years, yet a...
A tandem rhodium-catalyzed Bamford−Stevens/Claisen rearrangement is presented. The tandem reaction u...
A tandem rhodium-catalyzed Bamford−Stevens/Claisen rearrangement is presented. The tandem reaction u...
Diazocetonas e ilídeos β-cetossulfoxônios são precursores sintéticos bastantes versáteis e pode...
Copyright © ARKAT USA, Inc The document attached has been archived with permission from the publishe...
Many commercialized medicinal compounds are analogs of chemicals isolated from sources found in natu...
available in PMC 2014 November 1Highly substituted polycyclic aromatic and heteroaromatic compounds ...
A straightforward total synthesis of the cyclooctenoid sesquiterpene dactylol (1) and of 3a-epi-dact...
As the demand for pharmaceutical agents grow, efficient and cost effective syntheses of these target...
A set of mild processes for the conversion of vinyl cyclopropyl diazo ketones to highly functionaliz...
An investigation of the intramolecular cyclopropanation reactions of α-diazo-β-ketonitriles is repor...
We describe a photo-induced reaction for the in situ generation of highly reactive alkyl diazo compo...
We describe a photo-induced reaction for the in situ generation of highly reactive alkyl diazo compo...
Mild heating of diazo compounds in DMSO furnishes ketone products in moderate to excellent yields. T...
Mild heating of diazo compounds in DMSO furnishes ketone products in moderate to excellent yields. T...
Thesis advisor: Jason S. KingsburyThe research of diazoalkanes dates back more than 100 years, yet a...
A tandem rhodium-catalyzed Bamford−Stevens/Claisen rearrangement is presented. The tandem reaction u...
A tandem rhodium-catalyzed Bamford−Stevens/Claisen rearrangement is presented. The tandem reaction u...
Diazocetonas e ilídeos β-cetossulfoxônios são precursores sintéticos bastantes versáteis e pode...
Copyright © ARKAT USA, Inc The document attached has been archived with permission from the publishe...
Many commercialized medicinal compounds are analogs of chemicals isolated from sources found in natu...
available in PMC 2014 November 1Highly substituted polycyclic aromatic and heteroaromatic compounds ...
A straightforward total synthesis of the cyclooctenoid sesquiterpene dactylol (1) and of 3a-epi-dact...
As the demand for pharmaceutical agents grow, efficient and cost effective syntheses of these target...