5p Electronic properties of Gd in Gd@C82(OH)x studied by synchrotron radiation XPS
- Wang, S
- Zhao, Y
- Xing, G
- Yuan, H
- Jing, L
- Gao, X
- Cheng, Y
- Tang, J
Publication date
January 2007
DOI Publisher
Springer Science and Business Media LLC ISSN
0236-5731 Journal
Journal of Radioanalytical and Nuclear Chemistry Citation count (estimate)
8Abstract
The electronic properties of the metal atoms encaged in a fullerence cage were investigated using synchrotron X-ray photoelectron spectroscopy. Systematic variations in photoemission of valence band of Gd@C82, Gd@C 82(OH)12, and Gd@C82(OH)22 were observed in Gd 5p levels. The results suggest that the electronic properties of the inner metal atom can be efficiently modulated by surface chemistry of the fullerene cage. © 2007 Akadémiai Kiadó.link_to_subscribed_fulltex
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