Add to ORKGStable carbenes react with [Fe(cot)_2] in very different ways. Whereas the classical N-heterocyclic carbenes induce the formation of tetra- and trimetallic iron clusters, abnormal NHCs and carbocyclic carbenes (BACs) form mono- and bimetallic iron complexes. Cyclic (alkyl)(amino)carbenes (CAACs) react with [Fe(cot)_2] in a completely different manner, namely through outersphere [4+1] cycloaddition
The 3-coordinate 12 VE iron(II) benzyl complex [(nacnac)Fe(CH2Ph)] reacts with B(C6F5)(3) to yield a...
When a benzene solution containing the Fischer carbene complex [(CO)(6)Fe2Se2{mu-C(Ph)= C-C(OEt)=Cr(...
Two new sets of products [(CO)6Fe2EE'{μ-indanone}] (2a: E, E'=Se; 2b: E=S, E'=Se) and [(CO)6Fe2...
Stable carbenes react with [Fe(cot)_2] in very different ways. Whereas the classical N-heterocyclic ...
Compared with the enormous arsenal of catalysts used to produce organic compounds, complementary spe...
The synthesis, structures, and reactivity of dinuclear Fe<sup>0</sup> complexes of N-heterocyclic ca...
Despite their promising metal–ligand cooperative reactivity, PCcarbeneP pincer ligands are rarely r...
Addition of cyanide ions to the alkynyl(methoxy)carbene complexes [Fe2{μ-CN(Me)(R)}(μ-CO)...
A sterically demanding seven-membered expanded ring N-heterocyclic carbene (NHC) ligand allows acces...
The molecular structures, chemical bonding and magnetochemistry of the three-coordinate iron(II) NHC...
Treatment of readily available enynes with alkyl-Grignard reagents in the presence of catalytic amou...
Reaction of FeCl<sub>2</sub> with the chelating bis-<i>N</i>-heterocyclic carbene (NHC) bis-(<i>N</i...
A 9 ps (MLCT)-M-3 lifetime was achieved by a Fe-II complex based on C(NHC)boolean AND N(py)boolean A...
The 3-coordinate 12 VE iron(II) benzyl complex [(nacnac)Fe(CH2Ph)] reacts with B(C6F5)(3) to yield a...
When a benzene solution containing the Fischer carbene complex [(CO)(6)Fe2Se2{mu-C(Ph)= C-C(OEt)=Cr(...
Two new sets of products [(CO)6Fe2EE'{μ-indanone}] (2a: E, E'=Se; 2b: E=S, E'=Se) and [(CO)6Fe2...
Stable carbenes react with [Fe(cot)_2] in very different ways. Whereas the classical N-heterocyclic ...
Compared with the enormous arsenal of catalysts used to produce organic compounds, complementary spe...
The synthesis, structures, and reactivity of dinuclear Fe<sup>0</sup> complexes of N-heterocyclic ca...
Despite their promising metal–ligand cooperative reactivity, PCcarbeneP pincer ligands are rarely r...
Addition of cyanide ions to the alkynyl(methoxy)carbene complexes [Fe2{μ-CN(Me)(R)}(μ-CO)...
A sterically demanding seven-membered expanded ring N-heterocyclic carbene (NHC) ligand allows acces...
The molecular structures, chemical bonding and magnetochemistry of the three-coordinate iron(II) NHC...
Treatment of readily available enynes with alkyl-Grignard reagents in the presence of catalytic amou...
Reaction of FeCl<sub>2</sub> with the chelating bis-<i>N</i>-heterocyclic carbene (NHC) bis-(<i>N</i...
A 9 ps (MLCT)-M-3 lifetime was achieved by a Fe-II complex based on C(NHC)boolean AND N(py)boolean A...
The 3-coordinate 12 VE iron(II) benzyl complex [(nacnac)Fe(CH2Ph)] reacts with B(C6F5)(3) to yield a...
When a benzene solution containing the Fischer carbene complex [(CO)(6)Fe2Se2{mu-C(Ph)= C-C(OEt)=Cr(...
Two new sets of products [(CO)6Fe2EE'{μ-indanone}] (2a: E, E'=Se; 2b: E=S, E'=Se) and [(CO)6Fe2...