線型1,2-鄰二萘醌-1-肟(1-nqo)釕配合物的合成

By decarbonylated substitution reactions, rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime (1-nqo) are synthesized as trans-,cis- and cis-, cis-[Ru(1-nqo) 2(CO)(spy)] (3) and (4) which containing C 16 long alkyl chains in the molecules, cis-,cis-[Ru(1-nqo) 2(CO)(opy)] (5) and trans-,trans-[Ru(1-nqo) 2(opy) 2] (6) which containing C 18 long alkyl chains in the molecules. The complexes are characterized by IR, FAB MS, 1H- 1H COSY NMR and UV-visible spectra.報道了含C1 6長碳鏈線型 1,2 鄰二萘醌 1 肟 (1 nqo)釕配合物trans ,cis 及cis ,cis [Ru(1 nqo) 2 (CO) (spy) ](3)及 (4 ) ,含C1 8長碳鏈線型 1 nqo釕配合物cis ,cis [Ru(1 nqo) 2 (CO) (opy) ](5 ) ,trans ,trans [Ru(1 nqo) 2 (opy) 2 ](6 )的合成 .利用紅外、FAB質譜、核磁共振氫譜及紫外 -可見吸收光譜表征配合物的結構 ,利用1 H 1 H偶合二維核磁技術對核磁共振峰進行指