Two luminescent 2D layered copper(I)-olefin coordination polymers with high thermal stability
- You, XZ
- Che, CM
- Xiong, RG
- Zhang, J
- Chen, XT
- Xue, Z
Publication date
January 2001
DOI Publisher
American Chemical Society (ACS) ISSN
0276-7333 Journal
Organometallics Citation count (estimate)
35Abstract
The solvothermal reactions of 3-pyridylacrylic acid (3-HPYA) and 2-pyridylacrylic acid (2-HPYA) with Cu(CH 3CN) 4BF 4 yield two novel highly stable copper-(I)-olefin coordination polymers, [(3-PYA)Cu(I)]n (1) and {[(2-PYA)Cu(I)]·(H 2O)}n (2), respectively. Both polymers display 2D layered structures and yellow fluorescent emission in the solid state.link_to_subscribed_fulltex
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