Primary and secondary alcohols were oxidized using hydrogen peroxide as an oxygen donor and methyltrioxorhenium (MTO) as a catalyst. The methylrhenium bis-peroxide, CH3Re(O)(eta2-O2)2(H 2O), was the dominant and reactive form of the catalyst. A hydride abstraction mechanism was proposed for this reaction based on a number of isotopic labeling experiments and a linear free energy relationship correlation. This H 2O2/MTO oxidation system was also used in the oxidation of secondary hydroxylamines to form nitrones or oxoammonium, ions. A mechanism was proposed where the nitrogen lone pair performs a nucleophilic attack on the rhenium bound peroxo-oxygen. This mechanism is supported by isotopic and steric effects. Co-catalytic systems were explo...
Typescript (photocopy).Autoxidation of cobalt dioxygen complexes containing 2,2'-bipyridine, 1,10-ph...
The effect of driving force on the rate of oxidation of alcohols by trans-[RuVILO2]2+{L1 = (2,2′-bip...
Organic compounds containing carbon-metal bonds are called organometallic compounds. Such compounds ...
Conjugated dienes were oxidized by hydrogen peroxide with methylrhenium trioxide (MTO) as catalyst. ...
The complex [RuvL(O)]2+ {HL = [2-hydroxy-2-(2-pyridyl)ethyl]bis[2-(2-pyridyl)ethyl]amine} was found ...
Conjugated dienes were oxidized by hydrogen peroxide with methylrhenium trioxide as catalyst. As is ...
Many transition-metal complexes can perform catalytic oxidations, but their corresponding reaction p...
Many transition-metal complexes can perform catalytic oxidations, but their corresponding reaction p...
Methylrhenium dioxide (MDO), prepared in aqueous solution from the reaction of methylrhenium trioxid...
190 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1985.Oxidations are key steps in t...
The chemistry of chromium-oxygen compounds has been investigated. The previously-characterized super...
This thesis describes the development and study of catalysts for redox reactions, which either utili...
Dimethylacetamide (DMA) solvent is oxidized catalytically to CH₃CON(CH₃)CH₂OOH and CH₃CON(CH₃)CHO un...
trioxide have been determined. They indicate a mechanism involving nucleophilic attack. The protons ...
Typescript (photocopy).Autoxidation of cobalt dioxygen complexes containing 2,2'-bipyridine, 1,10-ph...
Typescript (photocopy).Autoxidation of cobalt dioxygen complexes containing 2,2'-bipyridine, 1,10-ph...
The effect of driving force on the rate of oxidation of alcohols by trans-[RuVILO2]2+{L1 = (2,2′-bip...
Organic compounds containing carbon-metal bonds are called organometallic compounds. Such compounds ...
Conjugated dienes were oxidized by hydrogen peroxide with methylrhenium trioxide (MTO) as catalyst. ...
The complex [RuvL(O)]2+ {HL = [2-hydroxy-2-(2-pyridyl)ethyl]bis[2-(2-pyridyl)ethyl]amine} was found ...
Conjugated dienes were oxidized by hydrogen peroxide with methylrhenium trioxide as catalyst. As is ...
Many transition-metal complexes can perform catalytic oxidations, but their corresponding reaction p...
Many transition-metal complexes can perform catalytic oxidations, but their corresponding reaction p...
Methylrhenium dioxide (MDO), prepared in aqueous solution from the reaction of methylrhenium trioxid...
190 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1985.Oxidations are key steps in t...
The chemistry of chromium-oxygen compounds has been investigated. The previously-characterized super...
This thesis describes the development and study of catalysts for redox reactions, which either utili...
Dimethylacetamide (DMA) solvent is oxidized catalytically to CH₃CON(CH₃)CH₂OOH and CH₃CON(CH₃)CHO un...
trioxide have been determined. They indicate a mechanism involving nucleophilic attack. The protons ...
Typescript (photocopy).Autoxidation of cobalt dioxygen complexes containing 2,2'-bipyridine, 1,10-ph...
Typescript (photocopy).Autoxidation of cobalt dioxygen complexes containing 2,2'-bipyridine, 1,10-ph...
The effect of driving force on the rate of oxidation of alcohols by trans-[RuVILO2]2+{L1 = (2,2′-bip...
Organic compounds containing carbon-metal bonds are called organometallic compounds. Such compounds ...