Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?

Burkart, Stefan
Blessing, Nico
Klipp, Björn
Müller, Jürgen
Ganteför, Gerd
Seifert, Gotthard

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Publication date

January 1999

DOI

10.1016/S0009-2614(98)01428-6

Publisher

Elsevier BV

Abstract

Photoelectron spectra of mass-separated, negatively charged, bare and reacted aluminium clusters AlnHm− (n=12 14, m=0 2) are presented and compared to the results of corresponding calculations. A large HOMO LUMO gap of 1.4 eV is found for the neutral Al13H cluster, indicating an extraordinarily high stability of this cluster. Adsorption of a second hydrogen atom results in the disappearance of the gap

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Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?

Abstract

Extracted data

Experimental verification of the high stability of Al13H : a building block of a new type of cluster material?

Abstract

Extracted data

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