We use video microscopy to study a two-dimensional (2D) model fluid of charged colloidal particles suspended in water and compute the pressure from the measured particle configurations. Direct experimental control over the particle density by means of optical tweezers allows the precise measurement of pressure as a function of density. We compare our data with theoretical predictions for the equation of state, the pair-correlation function and the compressibility of a hard-disc fluid and find good agreement, both for the fluid and the solid phase. In particular, the location of the transition point agrees well with results from Monte Carlo simulations.publishe
22 pags., 14 figs.We use theoretical and Monte Carlo computer simulations to study thermodynamic and...
New molecular simulation data are reported for the compressibility factors of hard spheres covering ...
Hard-sphere molecular dynamics (MD) simulation results, with six-figure accuracy in the thermodynami...
Recently, we have shown how to measure thermodynamic properties of colloidal hard sphere suspensions...
Recently, we have shown how to measure thermodynamic properties of colloidal hard sphere suspensions...
We use the Potential Distribution Theorem to evaluate distribution functions from equilibrium config...
In the presence of a non-adsorbing polymer, monodisperse rod-like colloids assemble into one-rod-len...
We apply Henderson's method for measuring the cavity distribution function y(r) [J. Henderson, Mol. ...
We apply Henderson’s method for measuring the cavity distribution function y(r) [J. Henderson, Mol. ...
We report the direct measurement of thermodynamic properties of colloidal hard spheres by optical mi...
Two-dimensional hard-particle systems are rather easy to simulate but surprisingly difficult to trea...
A large variety of engaging phenomena, ranging from crystallization in protein solutions to the form...
International audienceWe present a comparison of experimentally and theoretically determined osmotic...
We present a comparison of experimentally and theoretically determined osmotic pressures for various...
Colloidal systems are often modelled as fluids of hard particles (possibly with an ad-ditional soft ...
22 pags., 14 figs.We use theoretical and Monte Carlo computer simulations to study thermodynamic and...
New molecular simulation data are reported for the compressibility factors of hard spheres covering ...
Hard-sphere molecular dynamics (MD) simulation results, with six-figure accuracy in the thermodynami...
Recently, we have shown how to measure thermodynamic properties of colloidal hard sphere suspensions...
Recently, we have shown how to measure thermodynamic properties of colloidal hard sphere suspensions...
We use the Potential Distribution Theorem to evaluate distribution functions from equilibrium config...
In the presence of a non-adsorbing polymer, monodisperse rod-like colloids assemble into one-rod-len...
We apply Henderson's method for measuring the cavity distribution function y(r) [J. Henderson, Mol. ...
We apply Henderson’s method for measuring the cavity distribution function y(r) [J. Henderson, Mol. ...
We report the direct measurement of thermodynamic properties of colloidal hard spheres by optical mi...
Two-dimensional hard-particle systems are rather easy to simulate but surprisingly difficult to trea...
A large variety of engaging phenomena, ranging from crystallization in protein solutions to the form...
International audienceWe present a comparison of experimentally and theoretically determined osmotic...
We present a comparison of experimentally and theoretically determined osmotic pressures for various...
Colloidal systems are often modelled as fluids of hard particles (possibly with an ad-ditional soft ...
22 pags., 14 figs.We use theoretical and Monte Carlo computer simulations to study thermodynamic and...
New molecular simulation data are reported for the compressibility factors of hard spheres covering ...
Hard-sphere molecular dynamics (MD) simulation results, with six-figure accuracy in the thermodynami...