Add to ORKGRates of ring inversion of 1,1-difluorocyclodecane were obtained from line-shape changes in the low-temperature ^(19)F nmr spectra. At -135º, the free energy of activation was 5.7 kcal/mol. The results are interpreted in terms of a boat-chair-boat conformation. Possible pathways for effecting ring inversion are discussed
On cooling 3,3-difluoro-trans-cyclodecene from room temperature to - 152º, three different processes...
In a recent communication, the barrier to chair-chair interconversion in 1,1 -dimethyl-4,4-dibenzylc...
The fluorine n.m.r. spectrum of fluorocyclootatetraene has been shown to be temperature dependent be...
Rates of ring inversion of 1,1-difluorocyclodecane were obtained from line-shape changes in the low-...
A study of the temperature dependence of the ^(19)F nuclear magnetic resonance spectra of 1,1-difluo...
Fluorine magnetic resonance spectroscopy has been used to determine the rates of ring inversion of y...
Kinetic parameters for ring inversion of perfluorocyclohexene and 1,2-dichlorooctafluorocyclohexene ...
Rates of ring inversion and conformational equilibria of gem-fluorocyclohexanes carrying various sub...
The rate of ring inversion in 3,5,7-cyclooctatrienone was determined by the temperature dependence o...
The rate of ring inversion and conformational equilibration of 5,5-difluoro-cis-hydrindahn as been d...
Low-temperature fluorine magnetic resonance spectroscopy has been used to investigate the conformati...
The rates of ring inversion and conformational equilibration of 6,6-difluoro-cis-decal-2-one and 10-...
Fluorine magnetic resonance spectroscopy has been used to measure the rates of inversion of 4,4-difl...
Conformational equilibrium in medium-sized rings has been investigated by the temperature variation ...
A study of the temperature dependence of the ^(19)F nuclear magnetic resonance (nmr) spectra of 4,4-...
On cooling 3,3-difluoro-trans-cyclodecene from room temperature to - 152º, three different processes...
In a recent communication, the barrier to chair-chair interconversion in 1,1 -dimethyl-4,4-dibenzylc...
The fluorine n.m.r. spectrum of fluorocyclootatetraene has been shown to be temperature dependent be...
Rates of ring inversion of 1,1-difluorocyclodecane were obtained from line-shape changes in the low-...
A study of the temperature dependence of the ^(19)F nuclear magnetic resonance spectra of 1,1-difluo...
Fluorine magnetic resonance spectroscopy has been used to determine the rates of ring inversion of y...
Kinetic parameters for ring inversion of perfluorocyclohexene and 1,2-dichlorooctafluorocyclohexene ...
Rates of ring inversion and conformational equilibria of gem-fluorocyclohexanes carrying various sub...
The rate of ring inversion in 3,5,7-cyclooctatrienone was determined by the temperature dependence o...
The rate of ring inversion and conformational equilibration of 5,5-difluoro-cis-hydrindahn as been d...
Low-temperature fluorine magnetic resonance spectroscopy has been used to investigate the conformati...
The rates of ring inversion and conformational equilibration of 6,6-difluoro-cis-decal-2-one and 10-...
Fluorine magnetic resonance spectroscopy has been used to measure the rates of inversion of 4,4-difl...
Conformational equilibrium in medium-sized rings has been investigated by the temperature variation ...
A study of the temperature dependence of the ^(19)F nuclear magnetic resonance (nmr) spectra of 4,4-...
On cooling 3,3-difluoro-trans-cyclodecene from room temperature to - 152º, three different processes...
In a recent communication, the barrier to chair-chair interconversion in 1,1 -dimethyl-4,4-dibenzylc...
The fluorine n.m.r. spectrum of fluorocyclootatetraene has been shown to be temperature dependent be...